Synthesis and electrochemical investigations of bis(salen) complex precursors allowing the formation of a ladder-type polymer

被引：30

作者：

Aubert, PH ^{[1
]}

Audebert, P

Roche, M

Capdevielle, P

Maumy, M

Ricart, G

机构：

[1] Univ Franche Comte, Lab Chim & Electrochim Mol, F-25030 Cachan, France

[2] ENS, UMR 8531, CNRS, PPSM, F-94235 Cachan, France

[3] Ecole Super Phys & Chim Ind Ville Paris, CNRS, ESA 7084, Chim Organ Lab, F-75231 Paris 05, France

[4] Univ Lille 1, CNRS, UPRESA 8009, Lab Chim Macromol, Lille, France

来源：

CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 06期

关键词：

D O I：

10.1021/cm010240t

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis and characterization of bis(salen)-type complexes are reported. Using a "template" method, bimetallic complexes as dyssymmetric ligands can easily be built, giving birth to an unprecedented class of metal Schiff-base salen complexes. Electrochemical investigations allow us to study the overoxidation process that occurs during the polymerization. Furthermore, chronoamperometry studies indicate higher kinetics of electron charge transfer as a proof of an improvement in the polymer framework.

引用

页码：2223 / 2230

页数：8

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