Cycloheptatrienyl, alkyl and aryl PCP-pincer complexes: Ligand backbone effects and metal reactivity

被引：148

作者：

Leis, Wolfgang ^{[1
]}

Mayer, Hermann A. ^{[1
]}

Kaska, William C. ^{[2
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

[2] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 15-17期

基金：

美国国家科学基金会;

关键词：

PCP-pincer ligands; C-H activation; N-H activation; CO2; activation; hydrides;

D O I：

10.1016/j.ccr.2008.02.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pincer complexes have developed into a class of compounds with a tremendous breadth of applications in organometallic chemistry and catalysis. In this article we have selected a few PCP-pincer ligand systems and demonstrate that small changes in the ligand backbone have a dramatic impact on the reactivity change of their metal complexes. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1787 / 1797

页数：11

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