Hydroaminomethylation of Isoprene: Recycling of the Homogeneous Rhodium Catalyst in Aqueous Biphasic Systems

被引：9
|
作者：
Behr, Arno [1 ]
Reyer, Sebastian [1 ]
Manz, Vanessa [1 ]
机构：
[1] Tech Univ Dortmund, Lehrstuhl Tech Chem A, D-44227 Dortmund, Germany
来源：
CHEMIE INGENIEUR TECHNIK | 2012年 / 84卷 / 1-2期
关键词：
Amine; Catalyst recycling; Diene; Hydroaminomethylation; Hydroformylation; Isoprene; VERSATILE ACCESS; OLEFINS;
D O I：
10.1002/cite.201100106
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The first aqueous, biphasic hydroaminomethylation of isoprene with morpholine was investigated. In addition to optimizing various reaction parameters the dependence of the n/iso selectivity of the reaction to the pH value was investigated. Furthermore, the recycling of the water-soluble homogeneous rhodium catalyst was a main emphasis of the research.
引用
收藏
页码：108 / 113
页数：6
相关论文
共 50 条
  • [41] Switching Mechanistic Pathways by Micellar Catalysis: A Highly Selective Rhodium Catalyst for the Hydroaminomethylation of Olefins with Anilines in Water
    Migliorini, Francesca
    Monciatti, Elisabetta
    Romagnoli, Giulia
    Parisi, Maria Laura
    Taubert, Julia
    Vogt, Matthias
    Langer, Robert
    Petricci, Elena
    ACS CATALYSIS, 2023, 13 (04) : 2702 - 2714
  • [42] Process for high quality biodiesel with homogeneous catalyst recycling
    Research Disclosure, 2006, (509): : 1160 - 1163
  • [43] A simple way of recycling of homogeneous catalyst in Suzuki reaction
    Manjunatha, Sulur G.
    Rangappa, Paramashivappa
    Sythana, Sureshkumar
    Babu, Sureshbabu M.
    Tadiparthi, Krishnaji
    Gundala, Chennakrishnareddy
    GREEN CHEMISTRY LETTERS AND REVIEWS, 2013, 6 (01) : 77 - 87
  • [44] Advanced pure component spectral identification for the homogeneous rhodium catalyzed hydroformylation of isoprene.
    Garland, M
    Chew, W
    Chen, L
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : A73 - A73
  • [45] PARTICLE PARTITIONING IN AQUEOUS BIPHASIC SYSTEMS
    HAWKER, DTL
    DAVIS, RH
    TODD, P
    JOHANSSON, G
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 94 - BIOT
  • [46] Extraction of phenols in the aqueous biphasic systems
    Materna, Katarzyna
    PRZEMYSL CHEMICZNY, 2013, 92 (09): : 1640 - 1642
  • [47] Aqueous biphasic hydroformylation catalyzed by rhodium carbonyl complexes modified with bioligands
    Paganelli, S.
    Marchetti, M.
    Bianchin, M.
    Bertucci, C.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 269 (1-2) : 234 - 239
  • [48] Aqueous Biphasic Hydroformylation of Oleyl Alcohol Catalyzed by Thermoregulated Rhodium Complex
    Fan Zhi KONG
    Chinese Chemical Letters, 2003, (09) : 917 - 919
  • [49] Aqueous biphasic hydroformylation of oleyl alcohol catalyzed by thermoregulated rhodium complex
    Kong, FZ
    Zheng, XL
    Jin, ZL
    CHINESE CHEMICAL LETTERS, 2003, 14 (09) : 917 - 919
  • [50] Kinetics of hydroformylation of styrene using homogeneous rhodium complex catalyst
    Nair, VS
    Mathew, SP
    Chaudhari, RV
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 143 (1-3) : 99 - 110
12345