Hydroaminomethylation of Isoprene: Recycling of the Homogeneous Rhodium Catalyst in Aqueous Biphasic Systems

被引：9
|
作者：
Behr, Arno [1 ]
Reyer, Sebastian [1 ]
Manz, Vanessa [1 ]
机构：
[1] Tech Univ Dortmund, Lehrstuhl Tech Chem A, D-44227 Dortmund, Germany
来源：
CHEMIE INGENIEUR TECHNIK | 2012年 / 84卷 / 1-2期
关键词：
Amine; Catalyst recycling; Diene; Hydroaminomethylation; Hydroformylation; Isoprene; VERSATILE ACCESS; OLEFINS;
D O I：
10.1002/cite.201100106
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The first aqueous, biphasic hydroaminomethylation of isoprene with morpholine was investigated. In addition to optimizing various reaction parameters the dependence of the n/iso selectivity of the reaction to the pH value was investigated. Furthermore, the recycling of the water-soluble homogeneous rhodium catalyst was a main emphasis of the research.
引用
收藏
页码：108 / 113
页数：6
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