Synthesis, Crystal Structure, and Spectroscopic Studies of N-(4-Bromobenzylidene)-N′-(2-Pyridyl) Hydrazine Schiff Base Molecule

被引：9

作者：

Tunc, Tuncay ^{[1
]}

Tezcan, Habibe ^{[2
]}

Sahin, Ertan ^{[3
]}

Dilek, Nefise ^{[4
]}

机构：

[1] Aksaray Univ, Dept Sci Educ, Fac Educ, TR-68100 Aksaray, Turkey

[2] Gazi Univ, Fac Educ, Dept Chem Educ, Ankara, Turkey

[3] Ataturk Univ, Fac Sci & Arts, Dept Chem, Erzurum, Turkey

[4] Aksaray Univ, Fac Sci & Arts, Dept Phys, TR-68100 Aksaray, Turkey

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2012年 / 552卷

关键词：

Condensation reaction; crystal structure; hydrazone; Schiff base; X-ray diffraction; X-RAY-STRUCTURE; COMPLEXES; COPPER(II); BEHAVIOR;

D O I：

10.1080/15421406.2011.591702

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new Schiff base complex N-(4-bromobenzylidene)-N'-(2-pyridyl) hydrazine, C12H10N3Br, has been synthesized and characterized by elemental analyses, mass, H-1 NMR, ultraviolet-visible (UV-VIS), and IR spectroscopy and single-crystal X-ray determination. The p-Br-benzene and pyridine rings are almost planar and the dihedral angle between the planes is 11.1(3)degrees. The crystal structure is stabilized by intermolecular N-H center dot center dot center dot N-Py hydrogen bonding interaction. X-ray diffraction analyses show that N-(4-bromobenzylidene)-N'-(2-pyridyl) hydrazine Schiff base molecule crystallizes in the monoclinic system, P2(1)/c space group, a = 5.611(5) angstrom, b = 19.566(5) angstrom, c = 10.715(5) angstrom, beta = 98.766(5)degrees, and V = 1162.60(12) angstrom(3).

引用

页码：194 / 208

页数：15

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