High iso-alkanes production from palmitic acid over bi-functional Ni/H-ZSM-22 catalysts

被引：31

作者：

Cao, Yaya ^{[1
,2
]}

Shi, Yanchun ^{[2
]}

Liang, Junmei ^{[2
]}

Wu, Yulong ^{[2
,3
]}

Huang, Shaobin ^{[1
,4
]}

Wang, Jianlong ^{[2
]}

Yang, Mingde ^{[2
]}

Hu, Husheng ^{[2
]}

机构：

[1] South China Univ Technol, Coll Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China

[2] Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China

[3] Beijing Engn Res Ctr Biofuels, Beijing 100084, Peoples R China

[4] Guangdong Prov Key Lab Atmospher Environm & Pollu, Guangzhou 510006, Guangdong, Peoples R China

来源：

CHEMICAL ENGINEERING SCIENCE | 2017年 / 158卷

基金：

中国国家自然科学基金;

关键词：

Palmitic acid; Iso-alkanes; Bi-functional catalysts; Ni; H-ZSM-22; DIESEL-LIKE HYDROCARBONS; OXIDE CATALYSTS; HYDRODEOXYGENATION; OIL; PYROLYSIS; NI; DEOXYGENATION; FUELS;

D O I：

10.1016/j.ces.2016.10.007

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Bi-functional Ni/H-ZSM-22 catalysts with melt infiltration, incipient wetness impregnation and wet impregnation methods, were used to catalyze palmitic acid. Compared to parent zeolite, there were decrease of relative crystallinity, some blockage effects of micro pores and less strong acid sites after Ni loading. The complete conversion of palmitic acid and 100% alkanes selectivity were achieved at lower temperature (200 degrees C). No deactivation was observed in five recycle reaction, indicating the excellent catalytic performance and stability of Ni/H-ZSM-22 catalysts. Higher reaction temperature (240-260 degrees C), more iso-alkanes/n-alkanes formed, while less C-16/C-15 produced. Additionally, the catalysts prepared by melt infiltration were more inclined to HDO routes and produced more iso-alkanes (0.8 mol ratio of iso-alkanes/n-alkanes) than their counterparts prepared by conventional impregnation methods.

引用

页码：188 / 195

页数：8

共 32 条

[1]

[Anonymous], CATAL SCI TECHNOL

[2] Nannochloropsis algae pyrolysis with ceria-based catalysts for production of high-quality bio-oils [J].

Aysu, Tevfik ;

Sanna, Aimaro .

BIORESOURCE TECHNOLOGY, 2015, 194 :108-116

[3] Catalytic hydroprocessing of fatty acid methyl esters to renewable alkane fuels over Ni/HZSM-5 catalyst [J].

Chen, Liangguang ;

Li, Huiwen ;

Fu, Junying ;

Miao, Changlin ;

Lv, Pengmei ;

Yuan, Zhenhong .

CATALYSIS TODAY, 2016, 259 :266-276

[4] Optimizing catalysis conditions to decrease aromatic hydrocarbons and increase alkanes for improving jet biofuel quality [J].

Cheng, Jun ;

Li, Tao ;

Huang, Rui ;

Zhou, Junhu ;

Cen, Kefa .

BIORESOURCE TECHNOLOGY, 2014, 158 :378-382

[5] Catalytic hydrodeoxygenation of palmitic acid over a bifunctional Co-doped MoO2/CNTs catalyst: an insight into the promoting effect of cobalt [J].

Ding, Ranran ;

Wu, Yulong ;

Chen, Yu ;

Chen, Hao ;

Wang, Jianlong ;

Shi, Yanchun ;

Yang, Mingde .

CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (07) :2065-2076

[6] Effective hydrodeoxygenation of palmitic acid to diesel-like hydrocarbons over MoO2/CNTs catalyst [J].

Ding, Ranran ;

Wu, Yulong ;

Chen, Yu ;

Liang, Junmei ;

Liu, Ji ;

Yang, Mingde .

CHEMICAL ENGINEERING SCIENCE, 2015, 135 :517-525

[7] Steam reforming of n-decane for H2 production over Ni modified La-Al2O3 catalysts: Effects of the active component Ni content [J].

Jiao, Yi ;

Du, Yongmei ;

Zhang, Jianwei ;

Li, Chunying ;

Xue, Yunna ;

Lu, Jian ;

Wang, Jianli ;

Chen, Yaoqiang .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2015, 116 :58-67

[8] Stability evaluation of fast pyrolysis oil from rice straw [J].

Li, Hao ;

Xia, Shuqian ;

Li, Yang ;

Ma, Peisheng ;

Zhao, Chuang .

CHEMICAL ENGINEERING SCIENCE, 2015, 135 :258-265

[9] Study on CO2 reforming of methane to syngas over Al2O3-ZrO2 supported Ni catalysts prepared via a direct sol-gel process [J].

Li, HS ;

Wang, JF .

CHEMICAL ENGINEERING SCIENCE, 2004, 59 (22-23) :4861-4867

[10] CO-PROX reactions on copper cerium oxide catalysts prepared by melt infiltration [J].

Li, Xiaobo ;

Quek, Xian-Yang ;

Ligthart, D. A. J. Michel ;

Guo, Meiling ;

Zhang, Yi ;

Li, Can ;

Yang, Qihua ;

Hensen, Emiel J. M. .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 123 :424-432

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