Synthesis, Structure, and Characterization of a Porous Metal-Organic Framework Based on Bimetallic Unit and Flexible Ligand

被引：2
作者：
Liu, Jian-Qiang [1 ]
Hu, Wu-Xin [2 ]
Wu, Tie [1 ]
机构：
[1] Guangdong Med Coll, Sch Pharm, Dongguan 523808, Peoples R China
[2] Wenzhou Med Coll, Inst Hlth & Environm Ecol, Wenzhou, Zhejiang, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 05期
关键词：
crystal structure; flexible ligand; porous channel; Zn(II) complex; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; CADMIUM(II);
D O I：
10.1080/15533174.2011.568430
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer of Zn(II), viz., {[ZnNa2(sdba)2 (DMF)]center dot 0.5DMF}n (sdba = 4,4'-sulfonyldibenzoate) (1), has been synthesized and structurally characterized by X-ray diffraction. Compound 1 adopts a novel 3D framework containing three types of nano-tube channels. Moreover, the sdba ligand exhibits very unusual coordinative mode as bridging node.
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页码：479 / 483
页数：5
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