Synthesis and spectroscopic characterization of a series of substituted cyclopentadienyl group 4 fluorides; Crystal structure of the acetylacetonato complex [(acac)(2)(eta-C(5)Me(5))Zr(mu-F)SnMe(3)Cl]

被引：33

作者：

Murphy, EF ^{[1
]}

Yu, PH ^{[1
]}

Dietrich, S ^{[1
]}

Roesky, HW ^{[1
]}

Parisini, E ^{[1
]}

Noltemeyer, M ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 09期

关键词：

D O I：

10.1039/dt9960001983

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of mono- and di-substituted cyclopentadienyl Group 4 fluorides [Ti{eta-C(5)H(3)R(R')-1,3}F-n(m)], (n = m = 2 and n = 1, m = 3; R = H or SiMe(3); R' = H, Me or SiMe(3)), [Ti(eta-C(5)Me(5))(2)F-2] and [Zr(eta-C5H5)(2)F-2] have been-prepared via the reaction of the corresponding chlorides with SnMe(3)F. The compounds have been characterized by means of H-1 and F-19 NMR, IR and mass spectroscopy and chemical analyses. The solvent dependence of the reactions using SnMe,F is discussed. To demonstrate the wide applicability of this fluorinating system the acetylacetonatofluoro complex [(acac)(2)(eta-C(5)Me(5))Zr(eta-F)SnMe(3)Cl] has been prepared and its crystal structure determined.

引用

页码：1983 / 1987

页数：5

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