Study of Cu(II) removal by Cystoseira crinitophylla biomass in batch and continuous flow biosorption

被引:55
作者
Christoforidis, A. K. [1 ]
Orfanidis, S. [2 ]
Papageorgiou, S. K. [3 ]
Lazaridou, A. N. [1 ]
Favvas, E. P. [3 ]
Mitropoulos, A. Ch. [1 ]
机构
[1] Eastern Macedonia & Thrace Inst Technol, Hephaestus Lab, Dept Petr & Mech Engn, St Lucas 65404, Cavala, Greece
[2] Natl Agr Res Fdn NAGREF, Inst Piscatorial Res, Nea Peramos 64007, Cavala, Greece
[3] NCSR Demokritos, Inst Nanosci & Nanotechnol, Aghia Paraskevi 15341, Attica, Greece
关键词
Cystoseira; Seaweed; Heavy metals; Biosorption; Column; pH; HEAVY-METALS; AQUEOUS-SOLUTIONS; COPPER(II); SORPTION; IONS; BED; CADMIUM; SEAWEED; PHENOL; NICKEL;
D O I
10.1016/j.cej.2015.04.138
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Copper biosorption by Cystoseira crinitophylla dry biomass was studied in a batch sorption experiment as well as a continuous regenerable column configuration. The algal biomass showed a very high adsorption capacity of 160 mg g(-1) at 600 mg l(-1) equilibrium concentration at pH 4.5. Sorption isotherms were fitted with the Langmuir and Freundlich model equations showing very good agreement with the data. Flowthrough experiments were performed in a column containing Cystoseira protonated dry biomass. The data were fitted with the Thomas and Clark models for heterogenous ion exchange and the role of pH, flow rate, bed height and feed concentration was investigated. Regeneration studies of the column showed 100% efficiency even after 35 sorption/desorption cycles at pH 4.5 and 96% for pH 2.6. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:334 / 340
页数:7
相关论文
共 36 条
[1]  
Adamson A. V., 1990, PHYS CHEM SURFACES
[2]   Fixed-bed adsorption of reactive azo dye onto granular activated carbon prepared from waste [J].
Ahmad, A. A. ;
Hameed, B. H. .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 175 (1-3) :298-303
[3]   THE BIOSORPTION OF COPPER(II) BY C-VULGARIS AND Z-RAMIGERA [J].
AKSU, Z ;
SAG, Y ;
KUTSAL, T .
ENVIRONMENTAL TECHNOLOGY, 1992, 13 (06) :579-586
[4]   Biosorption of phenol by immobilized activated sludge in a continuous packed bed:: prediction of breakthrough curves [J].
Aksu, Z ;
Gönen, F .
PROCESS BIOCHEMISTRY, 2004, 39 (05) :599-613
[5]   Predictions of binary sorption isotherms for the sorption of heavy metals by pine bark using single isotherm data [J].
Al-Asheh, S ;
Banat, F ;
Al-Omari, R ;
Duvnjak, Z .
CHEMOSPHERE, 2000, 41 (05) :659-665
[6]  
[Anonymous], 1990, BIOSORPTION HEAVY ME
[7]  
[Anonymous], 2013, WATER BASIC INFORM R
[8]  
[Anonymous], 2012, ADSORPTION TECHNOLOG
[9]  
Antunes WM, 2003, ELECTRON J BIOTECHN, V6, P174, DOI 10.4067/S0717-34582003000300003
[10]   Lead and nickel removal using Microspora and Lemna minor [J].
Axtell, NR ;
Sternberg, SPK ;
Claussen, K .
BIORESOURCE TECHNOLOGY, 2003, 89 (01) :41-48