Heterodinuclear metal complexes of phenol-based compartmental macrocycles

被引：268

作者：

Okawa, H ^{[1
]}

Furutachi, H

Fenton, DE

机构：

[1] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 812, Japan

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

COORDINATION CHEMISTRY REVIEWS | 1998年 / 174卷

关键词：

heterodinuclear; macrocycle; compartmental ligands;

D O I：

10.1016/S0010-8545(97)00082-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article concerns recent progress in the derivation of heterodinuclear metal complexes from phenol-based compartmental macrocycles. Focus is placed on the design of unsymmetrical macrocycles whose two metal-binding sites, sharing two phenolic oxygens, are dissimilar with respect to the cavity size, coordination number, or the nature of donor atom. The stereochemistry, physicochemical properties and reactivities of the heterodinuclear complexes derived from these compartmental macrocycles are reviewed. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：51 / 75

页数：25

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