The role of chloride ion on the atmospheric corrosion of steel and corrosion resistance of Sn-bearing steel

被引：82

作者：

Kamimura, T. ^{[1
]}

Kashima, K. ^{[1
]}

Sugae, K. ^{[1
]}

Miyuki, H. ^{[1
]}

Kudo, T. ^{[1
]}

机构：

[1] Sumitomo Met Ind Ltd, Corp Res & Dev Labs, Amagasaki, Hyogo 6600891, Japan

来源：

CORROSION SCIENCE | 2012年 / 62卷

关键词：

Steel; Low alloy steel; X-ray diffraction; Atmospheric corrosion; Rust; THIN ELECTROLYTE LAYERS; HIGH-STRENGTH STEEL; HYDROGEN ENTRY; WEATHERING STEEL; RUST LAYER; PROTECTIVE ABILITY; IRON; MECHANISM; REDUCTION;

D O I：

10.1016/j.corsci.2012.04.049

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In order to clarify the role of chloride ion on the atmospheric corrosion of steels, the minute anode chamber simulating local anode sites on steels was set up, and the pH change was measured. The pH was affected by the chloride concentration, and decreased to 1.5 with the formation of beta-FeOOH. The role of chloride ion on the corrosion is discussed from the viewpoint of solubility and hydrolysis of Fe3+-species. An atmospheric corrosion model under high chloride content environments is proposed. Based on the model, it was found that Sn-bearing steel exhibits the superior atmospheric corrosion resistance. (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：34 / 41

页数：8

共 44 条

[1] Hydrogen entry into Fe and high strength steels under simulated atmospheric corrosion
Akiyama, Eiji
Li, Songjie
Shinohara, Tadashi
Zhang, Zuogui
Tsuzaki, Kaneaki
[J]. ELECTROCHIMICA ACTA, 2011, 56 (04) : 1799 - 1805
[2] Evaluation of hydrogen entry into high strength steel under atmospheric corrosion
Akiyama, Eiji
Matsukado, Katsuhiro
Wang, Maoqiu
Tsuzaki, Kaneaki
[J]. CORROSION SCIENCE, 2010, 52 (09) : 2758 - 2765
[3] BAES CF, 1986, HYDROLYSIS CATIONS, P228
[4] Corrosion protection and assessment of weathering steel highway structures
Damgaard, N.
Walbridge, S.
Hansson, C.
Yeung, J.
[J]. JOURNAL OF CONSTRUCTIONAL STEEL RESEARCH, 2010, 66 (10) : 1174 - 1185
[5] MECHANISM OF ATMOSPHERIC RUSTING
EVANS, UR
TAYLOR, CAJ
[J]. CORROSION SCIENCE, 1972, 12 (03) : 227 - &
[6] MECHANISM OF RUSTING
EVANS, UR
[J]. CORROSION SCIENCE, 1969, 9 (11) : 813 - &
[7] GATOS HC, 1956, CORROSION, V12, pT322
[8] Taxonomy for protective ability of rust layer using its composition formed on weathering steel bridge
Hara, Shuichi
Kamimura, Takayuki
Miyuki, Hideaki
Yamashita, Masato
[J]. CORROSION SCIENCE, 2007, 49 (03) : 1131 - 1142
[9] Hine F., 1973, J SOC MAT SCI JPN, V23, P654
[10] Active dissolution mechanisms of iron using EIS with channel flow double electrode. Influences of chloride and fluoride ions
Itagaki, M
Tagaki, M
Watanabe, K
[J]. ELECTROCHIMICA ACTA, 1996, 41 (7-8) : 1201 - 1207

← 1 2 3 4 5 →