Visible-light-driven photocatalytic and photoelectrochemical properties of porous SnSx(x=1,2) architectures

被引：116

作者：

Chao, Junfeng ^{[1
,2
]}

Xie, Zhong ^{[1
,2
]}

Duan, XianBao ^{[4
]}

Dong, Yuan ^{[1
,2
]}

Wang, Zhuoran ^{[1
,2
]}

Xu, Jing ^{[1
,2
]}

Liang, Bo ^{[1
,2
]}

Shan, Bin ^{[4
]}

Ye, Jinhua ^{[3
]}

Chen, Di ^{[1
,2
]}

Shen, Guozhen ^{[1
,2
]}

机构：

[1] HUST, WNLO, Wuhan 430074, Peoples R China

[2] HUST, Coll Optoelect Sci & Engn, Wuhan 430074, Peoples R China

[3] NIMS, Int Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050047, Japan

[4] HUST, Sch Mat Sci & Engn, Wuhan 430074, Peoples R China

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 09期

关键词：

HIGH-PERFORMANCE; PHOTOASSISTED DEGRADATION; HYDROTHERMAL SYNTHESIS; MEDIATED SYNTHESIS; DYE POLLUTANTS; RHODAMINE-B; TIO2; SNS2; NANOSTRUCTURES; IRRADIATION;

D O I：

10.1039/c2ce06586j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By using a facile and template-free polyol refluxing process, we reported the successful synthesis of porous SnS and SnS2 architectures on a large scale. The as-synthesized samples were characterized by using XRD, SEM, TEM, UV-vis DRS, Raman and N-2 adsorption-desorption analyses. Studies revealed that the as-synthesized SnS and SnS2 products mainly consist of porous flower-like microstructures with reasonable BET surface areas of 66 m(2) g(-1) and 33 m(2) g(-1), respectively. Photocatalytic properties of trace amounts of samples were investigated by photodegradation of MB and RhB under visible light irradiation. The photoelectrochemical properties of both samples were also studied by configuring the samples as photoelectrochemical (PEC) cells, exhibiting excellent photosensitivity and response with greatly enhanced I-on/off as high as 1.4 x 10(3), three orders of magnitude higher than previous work. The results indicate the potential applications of the SnSx nanostructures in visible-light-driven photocatalysts, high response photodetectors and other optoelectronic nanodevices.

引用

页码：3163 / 3168

页数：6

共 47 条

[41] Photocatalytic Remote Oxidation Induced by Visible Light [J].

Yang, Fei ;

Takahashi, Yukina ;

Sakai, Nobuyuki ;

Tatsuma, Tetsu .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (37) :18270-18274

[42] Encapsulation of TiO2(B) nanowire cores into SnO2/carbon nanoparticle shells and their high performance in lithium storage [J].

Yang, Zunxian ;

Du, Guodong ;

Guo, Zaiping ;

Yu, Xuebin ;

Chen, Zhixin ;

Guo, Tailiang ;

Zeng, Rong .

NANOSCALE, 2011, 3 (10) :4440-4447

[43] Photoelectrochemical Characterization of CuInSe2 and Cu(In1-xGax)Se2 Thin Films for Solar Cells [J].

Ye, Heechang ;

Park, Hyun S. ;

Akhavan, Vahid A. ;

Goodfellow, Brian W. ;

Panthani, Matthew G. ;

Korgel, Brian A. ;

Bard, Allen J. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (01) :234-240

[44] Photoassisted degradation of dye pollutants in aqueous TiO2 dispersions under irradiation by visible light [J].

Zhang, FL ;

Zhao, JC ;

Zang, L ;

Shen, T ;

Hidaka, H ;

Pelizzetti, E ;

Serpone, N .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 120 (1-3) :173-178

[45] Size-Tunable Hydrothermal Synthesis of SnS2 Nanocrystals with High Performance in Visible Light-Driven Photocatalytic Reduction of Aqueous Cr(VI) [J].

Zhang, Yong Cai ;

Li, Jing ;

Zhang, Ming ;

Dionysiou, Dionysios D. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (21) :9324-9331

[46] Size-controlled hydrothermal synthesis of Sns2 nanoparticles with high performance in visible light-driven photocatalytic degradation of aqueous methyl orange [J].

Zhang, Yong Cai ;

Du, Zhen Ni ;

Li, Kun Wei ;

Zhang, Ming .

SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 81 (01) :101-107

[47] Novel synthesis and high visible light photocatalytic activity of SnS2 nanoflakes from SnCl2•2H2O and S powders [J].

Zhang, Yong Cai ;

Du, Zhen Ni ;

Li, Shi Yin ;

Zhang, Ming .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 95 (1-2) :153-159

← 1 2 3 4 5 →