New organic magnetic anions TEMPO-CONA(CH2)nSO3- (n=0-3 for A=H, n=2 for A=CH3) and their TTF, TMTSF and/or BEDT-TTF salts

被引：19
作者：
Yamashita, A [1 ]
Akutsu, H [1 ]
Yamada, J [1 ]
Nakatsuji, S [1 ]
机构：
[1] Univ Hyogo, Grad Sch Mat Sci, Kamigori, Hyogo 6781297, Japan
来源：
POLYHEDRON | 2005年 / 24卷 / 16-17期
关键词：
organic magnetic conductor; organic free radical; TEMPO; X-ray crystallography; BEDT-TTF;
D O I：
10.1016/j.poly.2005.03.156
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Five TEMPO-containing anions TEMPO-CONA(CH2)(n)SO3- (H0(-), A = H, n = 0; H1(-), A H, n = 1; H2-, A = H, n = 2; H3(-), A = H, n = 3; M2(-), A = CH3, n = 2) have been prepared as PPh4 salts. So far three TTF salts ((TTF)(H1)(.) 2H(2)O, (TTF)(H2) (.) H2O, and (TTF)(M2) (.) 0.50H(2)O), one TMTSF salt ((TMTSF)(H1) (.) 2HO (.) PhCl), and one BEDT-TTF salt (alpha-(BEDT-TTF)(5)(H1)(2) (.) 6H2O have been obtained. Their crystal structures, electrical resistivities, and magnetic properties are reported. (c) 2005 Elsevier Ltd. All rights reserved.
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收藏
页码：2796 / 2802
页数：7
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