A dendron based on natural amino acids: Synthesis and behavior as an organogelator and lyotropic liquid crystal

被引：76
作者：
Ji, Y
Luo, YF
Jia, XR [1 ]
Chen, EQ
Huang, Y
Ye, C
Wang, BB
Zhou, QF
Wei, Y
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Dept Polymer Sci & Engn, Beijing 100871, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China
[3] Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 37期
关键词：
amino acids; dendrimers; gelators; liquid crystals; self-assembly;
D O I：
10.1002/anie.200500359
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
From linear to dendritic: Glycine is part of the predominant sequence in collagen proteins, and aspartate is similar to the repeating unit of poly(benzyl glutamate)s (PBG)s. Collagen and PBGs are linear peptides that self-organize into fibers and form liquid-crystalline phases and gel solvents. How would a molecule self-assemble if it was built by arranging Gly-Asp units in a dendritic way (see picture)? A dendron as both gelator and liquid crystal? (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6025 / 6029
页数：5
相关论文
共 81 条
  • [1] Abdallah DJ, 2000, ADV MATER, V12, P1237
  • [2] Responsive gels formed by the spontaneous self-assembly of peptides into polymeric beta-sheet tapes
    Aggeli, A
    Bell, M
    Boden, N
    Keen, JN
    Knowles, PF
    McLeish, TCB
    Pitkeathly, M
    Radford, SE
    [J]. NATURE, 1997, 386 (6622) : 259 - 262
  • [3] Dendrimers: a new class of nanoscopic containers and delivery devices
    Aulenta, F
    Hayes, W
    Rannard, S
    [J]. EUROPEAN POLYMER JOURNAL, 2003, 39 (09) : 1741 - 1771
  • [4] Dendrimers in drug research
    Boas, U
    Heegaard, PMH
    [J]. CHEMICAL SOCIETY REVIEWS, 2004, 33 (01) : 43 - 63
  • [5] Synthesis and chiroptical properties of a new type of chiral depsipeptide dendrons
    Buschhaus, B
    Bauer, W
    Hirsch, A
    [J]. TETRAHEDRON, 2003, 59 (22) : 3899 - 3915
  • [6] Synthesis of a novel dendritic liquid crystalline polymer showing a ferroelectric SmC* phase
    Busson, P
    Ihre, H
    Hult, A
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (35) : 9070 - 9071
  • [7] Choi IS, 1999, ANGEW CHEM INT EDIT, V38, P3078, DOI 10.1002/(SICI)1521-3773(19991018)38:20<3078::AID-ANIE3078>3.0.CO
  • [8] 2-3
  • [9] CHOI IS, 1999, ANGEW CHEM INT EDIT, V111, P3265
  • [10] Synthesis of a barbell-like triblock copolymer, poly(L-lysine) dendrimer-block-poly(ethylene glycol)-block-poly(L-lysine) dendrimer, and its self-assembly with plasmid DNA
    Choi, JS
    Joo, DK
    Kim, CH
    Kim, K
    Park, JS
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (03) : 474 - 480
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