Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

被引：45

作者：

Clingerman, Daniel J. ^{[1
,2
]}

Morris, William ^{[1
,2
]}

Mondloch, Joseph E. ^{[1
,2
]}

Kennedy, Robert D. ^{[1
,2
]}

Sarjeant, Amy A. ^{[1
,2
]}

Stern, Charlotte ^{[1
,2
]}

Hupp, Joseph T. ^{[1
,2
]}

Farha, Omar K. ^{[1
,2
,3
]}

Mirkin, Chad A. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

[3] Fac Sci, Dept Chem, Jeddah 22254, Saudi Arabia

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 30期

基金：

美国国家科学基金会;

关键词：

GAS-STORAGE; SEPARATION; ADSORPTION;

D O I：

10.1039/c4cc09212k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first tritopic carborane-based linker, H(3)BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu-3(BCA)(2)). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m(2) g(-1).

引用

页码：6521 / 6523

页数：3

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