Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

被引：45

作者：

Clingerman, Daniel J. ^{[1
,2
]}

Morris, William ^{[1
,2
]}

Mondloch, Joseph E. ^{[1
,2
]}

Kennedy, Robert D. ^{[1
,2
]}

Sarjeant, Amy A. ^{[1
,2
]}

Stern, Charlotte ^{[1
,2
]}

Hupp, Joseph T. ^{[1
,2
]}

Farha, Omar K. ^{[1
,2
,3
]}

Mirkin, Chad A. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

[3] Fac Sci, Dept Chem, Jeddah 22254, Saudi Arabia

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 30期

基金：

美国国家科学基金会;

关键词：

GAS-STORAGE; SEPARATION; ADSORPTION;

D O I：

10.1039/c4cc09212k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first tritopic carborane-based linker, H(3)BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu-3(BCA)(2)). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m(2) g(-1).

引用

页码：6521 / 6523

页数：3

共 32 条

[1] Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane [J].

Bae, Youn-Sang ;

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Mirkin, Chad A. ;

Hupp, Joseph T. ;

Snurr, Randall Q. .

CHEMICAL COMMUNICATIONS, 2008, (35) :4135-4137

[2] Separation of gas mixtures using Co(II) carborane-based porous coordination polymers [J].

Bae, Youn-Sang ;

Spokoyny, Alexander M. ;

Farha, Omar K. ;

Snurr, Randall Q. ;

Hupp, Joseph T. ;

Mirkin, Chad A. .

CHEMICAL COMMUNICATIONS, 2010, 46 (20) :3478-3480

[3] Adsorption of gases in multimolecular layers [J].

Brunauer, S ;

Emmett, PH ;

Teller, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319

[4] A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].

Chen, BL ;

Liang, CD ;

Yang, J ;

Contreras, DS ;

Clancy, YL ;

Lobkovsky, EB ;

Yaghi, OM ;

Dai, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393

[5] Synthesis and hydrogen sorption properties of carborane based metal-organic framework materials [J].

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Mulfort, Karen L. ;

Hawthorne, M. Frederick ;

Mirkin, Chad A. ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (42) :12680-+

[6]

Farha OK, 2010, NAT CHEM, V2, P944, DOI [10.1038/nchem.834, 10.1038/NCHEM.834]

[7] Reversible Anion Exchange and Catalytic Properties of Two Cationic Metal-Organic Frameworks Based on Cu(I) and Ag(I) [J].

Fei, Honghan ;

Rogow, David L. ;

Oliver, Scott R. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (20) :7202-7209

[8] Ultrahigh Porosity in Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Ko, Nakeun ;

Go, Yong Bok ;

Aratani, Naoki ;

Choi, Sang Beom ;

Choi, Eunwoo ;

Yazaydin, A. Oezguer ;

Snurr, Randall Q. ;

O'Keeffe, Michael ;

Kim, Jaheon ;

Yaghi, Omar M. .

SCIENCE, 2010, 329 (5990) :424-428

[9]

Grimes RN, 2011, CARBORANES, 2ND EDITION, P1

[10] New multigram-scale preparation of 1,10-dicarba-closo-decaborane [J].

Holub, J ;

Jelínek, T ;

Janousek, Z .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2002, 67 (07) :949-952

← 1 2 3 4 →