Carbon-Carbon Bond Forming Reactions via Photogenerated Intermediates

被引：952

作者：

Ravelli, Davide ^{[1
]}

Protti, Stefano ^{[1
]}

Fagnoni, Maurizio ^{[1
]}

机构：

[1] Univ Pavia, Dept Chem, Photogreen Lab, Viale Taramelli 12, I-27100 Pavia, Italy

来源：

CHEMICAL REVIEWS | 2016年 / 116卷 / 17期

关键词：

VISIBLE-LIGHT PHOTOREDOX; PHOTOINDUCED ELECTRON-TRANSFER; C-H BONDS; TRANSFER RADICAL-ADDITION; ALPHA-AMINO-ACIDS; DE-NOVO SYNTHESIS; SUNLIGHT-INDUCED FUNCTIONALIZATION; TITANIUM-DIOXIDE PHOTOCATALYSIS; DIELS-ALDER CYCLOADDITIONS; METAL-FREE;

D O I：

10.1021/acs.chemrev.5b00662

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present review offers an overview of the current approaches for the photochemical and photocatalytic generation of reactive intermediates and their application in the formation of carbon carbon bonds. Valuable synthetic targets are accessible, including arylation processes, formation of both carbo- and heterocycles, alpha- and beta-functionalization of carbonyls, and. addition reactions onto double and triple bonds. According to the recent advancements in the field of visible/solar light catalysis, a significant part of the literature reported herein involves radical ions and radicals as key intermediates, with particular attention to the most recent examples.,Synthetic application of carbenes, biradicals/radical pairs and carbocations have been also reported.

引用

页码：9850 / 9913

页数：64

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