Solvent-free synthesis of chiral molecularly imprinted polymers: Porosity control using a nano-sized solid porogen

被引：8

作者：

Duarte, Mariana ^{[1
,2
]}

Billing, Johan ^{[1
]}

Yilmaz, Ecevit ^{[1
]}

机构：

[1] MIP Technol AB, Box 737, S-22007 Lund, Sweden

[2] Lund Univ, Div Nanobiotechnol, Dept Biomed Engn, Box 118, S-22100 Lund, Sweden

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2016年 / 133卷 / 41期

关键词：

molecular recognition; morphology; nanoparticles; porous materials; STATIONARY PHASES; RECOGNITION; EPHEDRINE; CHROMATOGRAPHY; PERFORMANCE; FUTURE; POLYMERIZATION; RESOLUTION; BEADS;

D O I：

10.1002/app.44104

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Molecularly imprinted polymers (MIPs) have been synthesized in the absence of a solvent using fumed silica nanoparticles to create a porous network. The method employed led to a chiral imprinting effect and allowed for an excellent control over the internal morphology of imprinted and non-imprinted polymer (NIP) materials. The polymers possess high surface areas (>300 m(2)) and identical pore size (112 angstrom). The MIP exhibited an imprinting factor (IF) of 9 and a selectivity value (alpha) of 1.83 for (-)-ephedrine. (C) 2016 Wiley Periodicals, Inc.

引用

页数：5

共 50 条

[1] Recent advances in electrochemical sensors based on chiral and nano-sized imprinted polymers
Canfarotta, Francesco
Rapini, Riccardo
Piletsky, Sergey
CURRENT OPINION IN ELECTROCHEMISTRY, 2018, 7 : 146 - 152
[2] Surface Grafting of Polymers onto Nano-Sized Particles in Solvent-Free Dry-System and in Ionic Liquid
Norio TSUBOKAWA
复旦学报(自然科学版), 2005, (05) : 225 - 226
[3] Magnetic high throughput screening system for the development of nano-sized molecularly imprinted polymers for controlled delivery of curcumin
Piletska, Elena V.
Abd, Bashar H.
Krakowiak, Agata S.
Parmar, Anitha
Pink, Demi L.
Wall, Katie S.
Wharton, Luke
Moczko, Ewa
Whitcombe, Michael J.
Karim, Kal
Piletsky, Sergey A.
ANALYST, 2015, 140 (09) : 3113 - 3120
[4] Rapid solvent-free synthesis of nano-sized ZSM-5 with a low Si/Al ratio at 90 °C
Zhang, Lejian
Wang, Xinping
Shi, Chuan
INORGANIC CHEMISTRY FRONTIERS, 2022, 9 (09): : 1992 - 2000
[5] Highly efficient solvent-free synthesis of 1,3-diacylglycerols by lipase immobilised on nano-sized magnetite particles
Meng, Xiao
Xu, Gang
Zhou, Qin-Li
Wu, Jian-Ping
Yang, Li-Rong
FOOD CHEMISTRY, 2014, 143 : 319 - 324
[6] Micro- versus nano-sized molecularly imprinted polymers in MALDI-TOF mass spectrometry analysis of peptides
Cenci, Lucia
Bertolla, Maddalena
Anesi, Andrea
Ambrosi, Emmanuele
Guella, Graziano
Bossi, Alessandra Maria
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2017, 409 (26) : 6253 - 6261
[7] Micro- versus nano-sized molecularly imprinted polymers in MALDI-TOF mass spectrometry analysis of peptides
Lucia Cenci
Maddalena Bertolla
Andrea Anesi
Emmanuele Ambrosi
Graziano Guella
Alessandra Maria Bossi
Analytical and Bioanalytical Chemistry, 2017, 409 : 6253 - 6261
[8] Synthesis and Application of Different Nano-Sized Imprinted Polymers for the Preparation of Promethazine Membrane Electrodes and Comparison of Their Efficiencies
Alizadeh, Taher
Ganjali, Mohammad Reza
Akhoundian, Maedeh
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2012, 7 (08): : 7655 - 7674
[9] Synthesis of lab-in-a-pipette-tip extraction using hydrophilic nano-sized dummy molecularly imprinted polymer for purification and analysis of prednisolone
Arabi, Maryam
Ghaedi, Mehrorang
Ostovan, Abbas
Wang, Shaobin
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 480 : 232 - 239
[10] Nano-sized magnetic core-shell and bulk molecularly imprinted polymers for selective extraction of amiodarone from human plasma
Banan, Kamran
Ghorbani-Bidkorbeh, Fatemeh
Afsharara, Hanif
Hatamabadi, Dara
Landi, Behnaz
Kecili, Rustem
Sellergren, Borje
ANALYTICA CHIMICA ACTA, 2022, 1198

← 1 2 3 4 5 →