Effect of the addition of alkaline earth sulfates to mullite ceramics on the corrosion and wetting by Al-Mg alloy

被引:7
|
作者
Ibarra, M. N. [2 ]
Almanza, J. M. [1 ]
Cortes, D. A. [1 ]
Escobedo, J. C. [1 ]
Pech, M. [1 ]
Martinez, R. [1 ]
机构
[1] CINVESTAV, Unidad Saltillo, Ramos Arizpe 25900, Coahuila, Mexico
[2] SA CV, Corporac Mexicana Invest Mat, Saltillo 25290, Coahuila, Mexico
关键词
Wetting; Corrosion; Sessile drop test; Mullite; Al-Mg alloy; LOW-CEMENT CASTABLES; MOLTEN ALUMINUM; ALUMINOSILICATE REFRACTORIES; INTERFACIAL PHENOMENA; RESISTANCE;
D O I
10.1016/j.jeurceramsoc.2015.01.025
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Novel ceramics showing a high corrosion resistance were obtained by adding alkaline earth sulfates to mullite (Al6Si2O13). Powder samples of mullite, mullite-SrSO4 and mullite-BaSO4 were prepared. Disk pellets of 4 cm in diameter were conformed by uniaxial pressing at 78 MPa and sintered at 1450 degrees C for 6 h. Wetting experiments were carried out by the sessile drop test at 900 degrees C using an Al-7Mg alloy. After sintering, substrates of mullite, mullite-SrAl2Si2O8 or mullite-BaAl2Si2O8 were obtained. The contact angles between samples surface of alkaline earth sulfates containing mullite and molten alloy were higher than that corresponding to pure mullite, showing a non-wetting behavior. Cross-section analysis by SEM and EDS of samples after the wetting test showed that the corrosion products were spinel (MgAl2O4) and periclase (MgO). The BaAl2Si2O8-containing samples showed a higher corrosion resistance. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2189 / 2194
页数:6
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