Advances in the chemistry of organozinc reagents

被引：43

作者：

Dilman, Alexander D. ^{[1
]}

Levin, Vitalij V. ^{[1
]}

机构：

[1] ND Zelinskii Inst Organ Chem, Leninsky Prosp 47, Moscow 119991, Russia

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 36期

基金：

俄罗斯科学基金会;

关键词：

Organozinc reagents; Negishi cross-coupling; Transmetalation; Halogen/zinc exchange; HIGHLY SELECTIVE METALATIONS; COBALT-CATALYZED ADDITION; ZINC REAGENTS; ARYLZINC REAGENTS; 3-COMPONENT SYNTHESIS; ALKYL-HALIDES; MAGNESIUM; SECONDARY; BASE; ORGANOMETALLICS;

D O I：

10.1016/j.tetlet.2016.07.080

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In recent years, organozinc compounds have emerged as valuable reagents for transition metal catalyzed cross-couplings and nucleophilic addition reactions. Tolerance of organozincs to common electrophilic functional groups such as ketones, esters, and nitriles in combination with intrinsically high reactivity of carbon-zinc bond makes them ideal for the synthesis of complex functionalized products. This overview highlights advances in preparation and application of organozinc reagents reported over a period of last six years. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：3986 / 3992

页数：7

共 69 条

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