Synthesis and application of CoWO4 nanoparticles for degradation of methyl orange

被引:94
作者
Ahmadi, Farhad [1 ]
Rahimi-Nasrabadi, Mehdi [2 ,3 ]
Fosooni, Ali [4 ]
Daneshmand, Mohamadhossein [5 ]
机构
[1] Iran Univ Med Sci, Sch Pharm Int Campus, Dept Med Chem, Tehran, Iran
[2] Imam Hossein Univ, Dept Chem, Tehran, Iran
[3] Baghiatallah Univ Med Sci, Fac Pharm, Tehran, Iran
[4] Mapna Generator Mfg & Engn Co Pars, Tehran, Iran
[5] Islamic Azad Univ, Najaf Abad Branch, Young Researchers & Elite Club, Esfahan, Iran
关键词
PHOTOCATALYTIC DEGRADATION; ELECTROCHEMICAL SYNTHESIS; HYDROTHERMAL SYNTHESIS; NANOSTRUCTURES; COPPER; ROUTE; ZNWO4;
D O I
10.1007/s10854-016-5002-7
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In the current study, an attempt is made to synthesize cobalt tungstate (CoWO4) nanoparticles via a large-scale and facile precipitation method with the aid of cobalt (II) nitrate and sodium tungstate dihydrate in an aqueous solution. Besides, three surfactant agents such as sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, and ethylene diamine tetra acetic acid were used to investigate their effects on the morphology and particle size of CoWO4 nanoparticles. XRD, SEM, EDS, and UV-Vis spectroscopy were employed to characterize structural, morphological, and optical properties of CoWO4 nanoparticles. According to the vibrating sample magnetometer result, CoWO4 nanoparticles indicated a paramagnetic behavior at room temperature. In addition, methyl orange was chosen as a dye water pollution to evaluate its degradation by as-synthesize copper tungstate under ultraviolet light irradiation. Furthermore, the photocatalysis results reveal that the maximum decolorization of 70 % for methyl orange occurred with CoWO4 nanoparticles in 70 min under ultraviolet (UV) light irradiation.
引用
收藏
页码:9514 / 9519
页数:6
相关论文
共 28 条
  • [21] Hydrothermal synthesis and electronic properties of FeWO4 and CoWO4 nanostructures
    Rajagopal, S.
    Nataraj, D.
    Khyzhun, O. Yu.
    Djaoued, Yahia
    Robichaud, J.
    Mangalaraj, D.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 493 (1-2) : 340 - 345
  • [22] Study of growth imperfections, optical absorption, thermoluminescence and radiation hardness of CdWO4 crystals
    Sabharwal, SC
    Sangeeta
    [J]. JOURNAL OF CRYSTAL GROWTH, 1999, 200 (1-2) : 191 - 198
  • [23] Nanocrystalline MgAl2O4 as a Heterogeneous Nanocatalyst for the Synthesis of 2-Ketomethylquinolines Using Green Design Methodology
    Safari, J.
    Zarnegar, Z.
    [J]. JOURNAL OF NANOSTRUCTURES, 2013, 3 (02) : 191 - 197
  • [24] Synthesis and characterization of AgO nanostructures by precipitation method and its photocatalyst application
    Sobhani-Nasab, Ali
    Behpour, Mohsen
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2016, 27 (02) : 1191 - 1196
  • [25] Sodium dodecyl sulfate-assisted synthesis of CoWO4 nanorods
    Song, Xu Chun
    Yang, E.
    Ma, Rong
    Chen, Hai Fang
    Zhao, Yang
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 2008, 10 (04) : 709 - 713
  • [26] Low-temperature molten salt synthesis and characterization of CoWO4 nano-particles
    Song, Zuwei
    Ma, Junfeng
    Sun, Huyuan
    Sun, Yong
    Fang, Jingrui
    Liu, Zhengsen
    Gao, Chang
    Liu, Ye
    Zhao, Jingang
    [J]. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2009, 163 (01): : 62 - 65
  • [27] Characterization of CoWO4 nano-particles produced using the spray pyrolysis
    Thongtem, Somchai
    Wannapop, Surangkana
    Thongtem, Titipun
    [J]. CERAMICS INTERNATIONAL, 2009, 35 (05) : 2087 - 2091
  • [28] A facile hydrothennal route to the large-scale synthesis of CoWO4 nanorods
    Zhen, Liang
    Wang, Wen-Shou
    Xu, Cheng-Yan
    Shao, Wen-Zhu
    Qin, Lu-Chang
    [J]. MATERIALS LETTERS, 2008, 62 (10-11) : 1740 - 1742