A metallocene-complexed dibismuthene:: Cp2Zr(BiR)2 (CP = C5H5; R = C6H3-2,6-Mes2)

被引：32

作者：

Wang, YZ

Quillian, B

Yang, XJ

Wei, PR

Chen, ZF

Wannere, CS

Schleyer, PV ^{[1
]}

Robinson, GH

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

[2] Univ Georgia, Ctr Computat Chem, Athens, GA 30602 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 21期

关键词：

D O I：

10.1021/ja051704h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The zirconocene-complexed dibismuthene, Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes2), was prepared by the reaction of sodium metal with Cp2ZrCl2 and RBiCl2. The air- and moisture-sensitive dark reddish/brown compound is the first organometallic compound containing Bi-Zr bonds and the only example of a ZrBi2 ring. Moreover, our computations on associated model systems offer insight into the nature of the interaction of the heaviest dipnictene with a metallocene center. Copyright © 2005 American Chemical Society.

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页码：7672 / 7673

页数：2

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