Enzymatic synthesis and surface active properties of novel hemifluorinated mannose esters

被引：12
作者：
Favrelle, Audrey [1 ]
Boyere, Cedric [1 ]
Laurent, Pascal [2 ,3 ]
Broze, Guy [1 ]
Blecker, Christophe [4 ]
Paquot, Michel [2 ]
Jerome, Christine [1 ]
Debuigne, Antoine [1 ]
机构：
[1] Univ Liege, Inst Chem, Ctr Educ & Res Macromol CERM, B-4000 Liege, Belgium
[2] Univ Liege, Gembloux Agrobio Tech, Unit Biol & Ind Chem, B-5030 Gembloux, Belgium
[3] Univ Liege, Gembloux Agrobio Tech, Unit Gen & Organ Chem, B-5030 Gembloux, Belgium
[4] Univ Liege, Gembloux Agrobio Tech, Unit Food Technol, B-5030 Gembloux, Belgium
来源：
CARBOHYDRATE RESEARCH | 2011年 / 346卷 / 09期
关键词：
Lipase-catalysed esterification; Fluorinated sugar; Glycosurfactant; Surface active properties; LIPASE-CATALYZED SYNTHESIS; SUGAR ESTERS; CARBOHYDRATE; SUCROSE;
D O I：
10.1016/j.carres.2011.04.004
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The lipase-catalysed esterification of sugars with hemifluorinated acid derivatives is reported for the first time. A series of mannose modified derivatives having fluorinated chains with different length have been prepared accordingly in moderate yield. A preliminary evaluation of the surface active properties of these hemifluorinated mannose esters revealed their ability to reduce the surface tension of water much more efficiently than their aliphatic counterparts. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1161 / 1164
页数：4
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