Synthesis and crystal structure of d-f heteronuclear Gd(III)-Co(II) system

被引：9
|
作者：
Wu, Bin [1 ]
机构：
[1] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 16期
关键词：
gadolinium; cobalt; heteronuclear; crystal structure; magnetic properties;
D O I：
10.1080/00958970801947462
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A carboxylate-bridged Co(II)-Gd(III) complex, [(bipy)CoL3Gd(NO3)L3Co(bipy)] (HL = alpha-methylacrylic acid, bipy = 2,2'-bipyridine), was prepared and characterized. Single crystal X-ray analysis reveals that the complex assumes a carboxylate-bridged CoGdCo unit. Magnetic measurements showed chi T-m decreases when the temperature is lowered.
引用
收藏
页码：2558 / 2562
页数：5
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