Synthesis and crystal structure of Ni(II) complexes of 2′-(3,5-dibromo-2-hydroxybenzylidene)-3,5-dihydroxybenzoylhydrazide

被引：2
|
作者：
Yang, Jian-Guo [1 ]
Pan, Fu-You [1 ]
Jia, Wen-Ping [1 ]
Li, Fang [1 ]
机构：
[1] Taizhou Univ, Dept Chem, Taizhou 317000, Zhejiang, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 11期
关键词：
nickel(II); 3,5-dihydroxybenzoylhydrazide; crystal structure; synthesis;
D O I：
10.1080/00958970701746659
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new mononuclear nickel(II) complex incorporating a Schiff-base ligand, [NiL2](DMF)(4) (HL = 2'-(3,5-dibromo-2-hydroxybenzylidene)-3,5-dihydroxybenzoylhydrazide), has been synthesized and characterized by IR, UV-Vis, elemental analysis and X-ray crystal structure analysis. HL is an anionic tridentate ligand. The nickel atom is hexacoordinated with two oxygen atoms from keto group and two oxygen atoms from hydroxy group and two nitrogen atoms from amide, with the two nitrogen atoms occupying the axial positions forming a distorted octahedral coordination sphere.
引用
收藏
页码：1759 / 1764
页数：6
相关论文
共 50 条
  • [41] Crystal structure of N '-[(E)-3,5-dichloro2-hydroxybenzylidene]-4-nitrobenzo-hydrazide dimethylformamide monosolvate
    Joseph, Ribitha
    Sajitha, N. R.
    Sithambaresan, M.
    Seena, E. B.
    Kurup, M. R. Prathapachandra
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O826 - U314
  • [42] Synthesis and Crystal Structure of Nickle 3,5-Pyridinedicarboxylates
    Jin Qiang
    Zhao Jiao
    Shi Xin
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2010, 31 (08): : 1496 - 1501
  • [43] Synthesis and structure of the Mn(II) complexes with tripyrazolylborate ligands:: Mn[HB(pz)3]2 and Mn[HB(3,5-Me2-pz)3]2
    Xing, YH
    Aoki, K
    Bai, FY
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2004, 34 (07): : 1149 - 1163
  • [44] Synthesis, crystal structure and electrochemical properties of complex [Ni(phen)2(3,5-DMBA)](m-MBA)2(H2O)2
    Yang, YQ
    Li, CH
    Guo, DC
    Li, W
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (03) : 555 - 558
  • [45] Synthesis and Crystal Structure of Picrates of 3,5-Diamino-1,2,4-triazole
    赵鹏
    任莹辉
    李丹
    赵风起
    仪建华
    宋纪蓉
    马海霞
    结构化学, 2010, 29 (06) : 957 - 961
  • [46] Synthesis and Crystal Structure of Picrates of 3,5-Diamino-1,2,4-triazole
    Zhao Peng
    Ren Ying-Hui
    Li Dan
    Zhao Feng-Qi
    Yi Jian-Hua
    Song Ji-Rong
    Ma Hai-Xia
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (06) : 957 - 961
  • [47] Synthesis, Characterization, and Crystal Structures of Oxidovanadium(V) Complexes Derived from 2-Chloro-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide with Antimicrobial Activity
    Wu, S. M.
    Qiu, X. Y.
    Wang, J. C.
    Liu, S. J.
    He, L. Y.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (05) : 378 - 384
  • [48] Synthesis, Characterization, and Crystal Structures of Oxidovanadium(V) Complexes Derived from 2-Chloro-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide with Antimicrobial Activity
    S. M. Wu
    X. Y. Qiu
    J. C. Wang
    S. J. Liu
    L. Y. He
    Russian Journal of Coordination Chemistry, 2019, 45 : 378 - 384
  • [49] A novel synthesis and crystal structure of 3,5-substituted-3H-[1,3,4]thiadiazole-2-thione
    Jian, FF
    Zhao, PS
    Hou, YX
    Lu, LD
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2003, 24 (12) : 1843 - 1844
  • [50] Synthesis, Crystal Structure and Catalytic Property of an Oxovanadium(V) Complex Derived from N′-(3,5-Ditertbutyl-2-hydroxybenzylidene)-4-methoxybenzohydrazide
    Wang, Ying-Zhen
    Wang, Ping
    Li, Cong
    Su, Yong-Qing
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (06) : 927 - 930
12345