Synthesis and Characterization of Quaternary Ammonium-based Ionic Liquid

被引:4
作者
Dong, Sheying [1 ]
Zhang, Penghui [1 ]
Tian, Anxiang [1 ]
Huang, Tinglin [2 ]
机构
[1] Xian Univ Architecture & Technol, Coll Sci, Xian 710055, Peoples R China
[2] Xian Univ Architecture & Technol, Coll Environm & Municipal Engn, Xian 710055, Peoples R China
来源
MATERIALS SCIENCE AND INFORMATION TECHNOLOGY, PTS 1-8 | 2012年 / 433-440卷
基金
中国国家自然科学基金;
关键词
Quaternary ammonium salts; TFSI; Ionic liquid; Microwave-assisted synthesis; TEMPERATURE; SALTS;
D O I
10.4028/www.scientific.net/AMR.433-440.178
中图分类号
TP39 [计算机的应用];
学科分类号
081203 ; 0835 ;
摘要
A quaternary ammonium-based ionic liquid, n-butyl triethylammonium bis(trifluoromethane-sulfonyl) imide (N4222TFSI) was synthesized by using microwave and conventional methods. The structure of N4222TFSI was characterized by FT-IR, H-1-NMR and C-13-NMR. Its properties including viscosity, solubility, conductivity and density, were determined. Its applications as electrolyte and solvent for UV-VIS determination were also investigated.
引用
收藏
页码:178 / +
页数:3
相关论文
共 11 条
[1]   Hydrophobic, highly conductive ambient-temperature molten salts [J].
Bonhote, P ;
Dias, AP ;
Papageorgiou, N ;
Kalyanasundaram, K ;
Gratzel, M .
INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178
[2]   Synthesis, characterization and thermal properties of small R2R′2N+X--type quaternary ammonium halides [J].
Busi, S ;
Lahtinen, M ;
Mansikkamäki, H ;
Valkonen, J ;
Rissanen, K .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (06) :1722-1737
[3]   Improved preparations of ionic liquids using microwave irradiation [J].
Deetlefs, M ;
Seddon, KR .
GREEN CHEMISTRY, 2003, 5 (02) :181-186
[4]   THE USE OF MICROWAVE-OVENS FOR RAPID ORGANIC-SYNTHESIS [J].
GEDYE, R ;
SMITH, F ;
WESTAWAY, K ;
ALI, H ;
BALDISERA, L ;
LABERGE, L ;
ROUSELL, J .
TETRAHEDRON LETTERS, 1986, 27 (03) :279-282
[5]   Novel room temperature molten salt electrolyte based on LiTFSI and acetamide for lithium batteries [J].
Hu, YS ;
Li, H ;
Huang, XJ ;
Chen, LQ .
ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (01) :28-32
[6]   Carbon-ionic liquid double-layer capacitors [J].
Lewandowski, A ;
Galinski, M .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2004, 65 (2-3) :281-286
[7]   Electrochemical properties of imidazolium salt electrolytes for electrochemical capacitor applications [J].
McEwen, AB ;
Ngo, HL ;
LeCompte, K ;
Goldman, JL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (05) :1687-1695
[8]   Synthesis and Properties of Ambient Temperature Molten Salts Based on the Quaternary Ammonium Ion [J].
Sun, Jiazeng ;
MacFarlane, D. R. ;
Forsyth, M. .
IONICS, 1997, 3 (5-6) :356-362
[9]   Room-temperature ionic liquids. Solvents for synthesis and catalysis [J].
Welton, T .
CHEMICAL REVIEWS, 1999, 99 (08) :2071-2083
[10]   Temperature dependence of the electrochemical behavior of LiCoO2 in quaternary ammonium-based ionic liquid electrolyte [J].
Zheng, HH ;
Qin, JH ;
Zhao, Y ;
Abe, T ;
Ogumi, Z .
SOLID STATE IONICS, 2005, 176 (29-30) :2219-2226