Density, viscosity, refractive index, and speed of sound in binary mixtures of acrylonitrile with methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, heptan-1-ol, and butan-2-ol

被引:102
作者
Aralaguppi, MI [1 ]
Jadar, CV [1 ]
Aminabhavi, TM [1 ]
机构
[1] Karnatak Univ, Dept Chem, Dharwad 580003, Karnataka, India
关键词
D O I
10.1021/je9802219
中图分类号
O414.1 [热力学];
学科分类号
摘要
Density, viscosity, and refractive index data at 298.15, 303.15, and 308.15 K as well as the speed of sound at 298.15 K in the binary mixtures of acrylonitrile with methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, heptan-1-ol, and butan-2-ol are presented over the whole range of mixture compositions. From these results, excess molar volume, V-E, deviations in viscosity, Delta eta, molar refraction, Delta R, speed of sound, Delta u, and isentropic compressibility, Delta k(s) have been calculated. These quantities are fitted to a Redlich-Kister type polynomial equation to derive the binary coefficients and estimate the standard deviations between the experimental and calculated quantities.
引用
收藏
页码:216 / 221
页数:6
相关论文
共 14 条
[11]  
RIDDICK IA, 1986, PHYSICAL PROPERTIES, V2
[12]   Mixing properties of the system methyl acetate plus methanol plus ethanol at 298.15 K [J].
Rodriguez, A ;
Canosa, J ;
Orge, B ;
Iglesias, M ;
Tojo, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (06) :1446-1449
[13]   EXCESS MOLAR VOLUMES OF (ACRYLONITRILE plus AN N-ALKAN-1-OL) AT THE TEMPERATURE 298.15-K [J].
SANDHU, JS ;
SINGH, A .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (01) :81-84
[14]   DENSITY, VISCOSITY, SURFACE-TENSION, AND CARBON-DIOXIDE SOLUBILITY AND DIFFUSIVITY OF METHANOL, ETHANOL, AQUEOUS PROPANOL, AND AQUEOUS ETHYLENE-GLYCOL AT 25-DEGREES-C [J].
WON, YS ;
CHUNG, DK ;
MILLS, AF .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1981, 26 (02) :140-141