4-Chloro-N-(2,5-dimethylphenyl)-2-methylbenzenesulfonamide

被引：6

作者：

Rodrigues, Vinola Z. ^{[1
]}

Foro, Sabine ^{[2
]}

Gowda, B. Thimme ^{[1
]}

机构：

[1] Mangalore Univ, Dept Chem, Mangalore 574199, India

[2] Tech Univ Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

CH3; CL;

D O I：

10.1107/S1600536811040876

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, C15H16ClNO2S, contains three independent moleules. The conformation of the N-H bonds are anti to the ortho-methyl groups of the sulfonyl benzene rings in all the molecules. The sulfonyl and the aniline benzene rings are tilted relative to each other by 43.0 (2), 37.0 (2) and by 46.0 (1)degrees in the three molecules. In the crystal, intermolecular N-H center dot center dot center dot O hydrogen bonds link each of the molecules into centrosymmetric dimers.

引用

页码：O2891 / +

页数：15

共 12 条

[1] Hydrogen bonding in sulfonamides [J].

Adsmond, DA ;

Grant, DJW .

JOURNAL OF PHARMACEUTICAL SCIENCES, 2001, 90 (12) :2058-2077

[2]

[Anonymous], 2006, CrysAlis CCD and CrysAlis RED

[3] Structural systematics of 4,4′-disubstituted benzenesulfonamidobenzenes.: 1.: Overview and dimerbased isostructures [J].

Gelbrich, Thomas ;

Hursthouse, Michael B. ;

Threlfall, Terence L. .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2007, 63 (04) :621-632

[4] N-(4-bromophenyl)methanesulfonamide [J].

Gowda, B. Thimme ;

Foro, Sabine ;

Fuess, Hartmut .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :O2597-U1103

[5]

Gowda BT, 2000, Z NATURFORSCH A, V55, P721

[6] Kinetics of oxidation of acidic amino acids and their monoamides by N-chloroarylsulphonamides in aqueous acidic medium [J].

Gowda, BT ;

Shetty, M .

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2004, 17 (10) :848-864

[7] N-(2-chlorophenyl)benzenesulfonamide [J].

Perlovich, GL ;

Tkachev, VV ;

Schaper, KJ ;

Raevsky, OA .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 :O780-O782

[8] 4-Chloro-N-(2,3-dimethylphenyl)-2-methylbenzenesulfonamide [J].

Rodrigues, Vinola Z. ;

Foro, Sabine ;

Gowda, B. Thimme ;

Shakuntala, K. .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :O2674-+

[9]

Savitha M. B., 2006, Z NATURFORSCH A, V61, P600

[10] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

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