Unbalanced MOF-on-MOF growth for the production of a lopsided core-shell of MIL-88B@MIL-88A with mismatched cell parameters

被引：61
作者：
Kim, Dooyoung [1 ]
Lee, Gihyun [1 ]
Oh, Sojin [1 ]
Oh, Moonhyun [1 ]
机构：
[1] Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 01期
基金：
新加坡国家研究基金会;
关键词：
METAL-ORGANIC-FRAMEWORK; CONSTRUCTION; NANOCRYSTALS; FABRICATION; PARTICLES; TEMPLATE; POROSITY;
D O I：
10.1039/c8cc08456d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The unbalanced MOF-on-MOF growth of MIL-88A on the MIL-88B template, where both MOFs have a similar three-dimensional hexagonal structure but with mismatched cell parameters, results in the formation of an atypical lopsided core-shell of MIL-88B@MIL-88A with an off-centered core. The formation mechanism of the lopsided core-shell of MIL-88B@MIL-88A is verified via monitoring the growth process.
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收藏
页码：43 / 46
页数：4
相关论文
共 27 条
[1]   Liquid phase epitaxial growth of heterostructured hierarchical MOF thin films [J].
Chernikova, Valeriya ;
Shekhah, Osama ;
Spanopoulos, Ioannis ;
Pantelis, N. Trikalitis B. ;
Eddaoudi, Mohamed .
CHEMICAL COMMUNICATIONS, 2017, 53 (46) :6191-6194
[2]   Dual Changes in Conformation and Optical Properties of Fluorophores within a Metal-Organic Framework during Framework Construction and Associated Sensing Event [J].
Cho, Won ;
Lee, Hee Jung ;
Choi, Goeun ;
Choi, Sora ;
Oh, Moonhyun .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (35) :12201-12204
[3]   Coordination polymer nanorods of Fe-MIL-88B and their utilization for selective preparation of hematite and magnetite nanorods [J].
Cho, Won ;
Park, Seungjin ;
Oh, Moonhyun .
CHEMICAL COMMUNICATIONS, 2011, 47 (14) :4138-4140
[4]   Isotropic and Anisotropic Growth of Metal-Organic Framework (MOF) on MOF: Logical Inference on MOF Structure Based on Growth Behavior and Morphological Feature [J].
Choi, Sora ;
Kim, Taeho ;
Ji, Hoyeon ;
Lee, Hee Jung ;
Oh, Moonhyun .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (43) :14434-14440
[5]  
Farha OK, 2010, NAT CHEM, V2, P944, DOI [10.1038/NCHEM.834, 10.1038/nchem.834]
[6]   "Heterogeneity within Order" in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Mueller, Ulrich ;
Yaghi, Omar M. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (11) :3417-3430
[7]   Ultrahigh Porosity in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Ko, Nakeun ;
Go, Yong Bok ;
Aratani, Naoki ;
Choi, Sang Beom ;
Choi, Eunwoo ;
Yazaydin, A. Oezguer ;
Snurr, Randall Q. ;
O'Keeffe, Michael ;
Kim, Jaheon ;
Yaghi, Omar M. .
SCIENCE, 2010, 329 (5990) :424-428
[8]   Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core-Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship [J].
Furukawa, Shuhei ;
Hirai, Kenji ;
Nakagawa, Keiji ;
Takashima, Yohei ;
Matsuda, Ryotaro ;
Tsuruoka, Takaaki ;
Kondo, Mio ;
Haruki, Rie ;
Tanaka, Daisuke ;
Sakamoto, Hirotoshi ;
Shimomura, Satoru ;
Sakata, Osami ;
Kitagawa, Susumu .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (10) :1766-1770
[9]   CoreShell Noble-Metal@Metal-Organic-Framework Nanoparticles with Highly Selective Sensing Property [J].
He, Liangcan ;
Liu, Yong ;
Liu, Jingzhu ;
Xiong, Yansong ;
Zheng, Jianzhong ;
Liu, Yaling ;
Tang, Zhiyong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (13) :3741-3745
[10]   Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels [J].
Herm, Zoey R. ;
Wiers, Brian M. ;
Mason, Jarad A. ;
van Baten, Jasper M. ;
Hudson, Matthew R. ;
Zajdel, Pawel ;
Brown, Craig M. ;
Masciocchi, Norberto ;
Krishna, Rajamani ;
Long, Jeffrey R. .
SCIENCE, 2013, 340 (6135) :960-964
123