Unbalanced MOF-on-MOF growth for the production of a lopsided core-shell of MIL-88B@MIL-88A with mismatched cell parameters

被引：61
|
作者：
Kim, Dooyoung [1 ]
Lee, Gihyun [1 ]
Oh, Sojin [1 ]
Oh, Moonhyun [1 ]
机构：
[1] Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 01期
基金：
新加坡国家研究基金会;
关键词：
METAL-ORGANIC-FRAMEWORK; CONSTRUCTION; NANOCRYSTALS; FABRICATION; PARTICLES; TEMPLATE; POROSITY;
D O I：
10.1039/c8cc08456d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The unbalanced MOF-on-MOF growth of MIL-88A on the MIL-88B template, where both MOFs have a similar three-dimensional hexagonal structure but with mismatched cell parameters, results in the formation of an atypical lopsided core-shell of MIL-88B@MIL-88A with an off-centered core. The formation mechanism of the lopsided core-shell of MIL-88B@MIL-88A is verified via monitoring the growth process.
引用
收藏
页码：43 / 46
页数：4
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