Phase relation and microstructure in multi-phase intermetallic alloys based on Ni3Si-Ni3Ti-Ni3Nb pseudo-ternary alloy system

被引：49
作者：
Tomihisa, K [1 ]
Kaneno, Y [1 ]
Takasugi, T [1 ]
机构：
[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Met & Mat Sci, Sakai, Osaka 5998531, Japan
来源：
INTERMETALLICS | 2004年 / 12卷 / 03期
关键词：
multiphase intermetallics; phase diagram; microstructure; phase stability; prediction;
D O I：
10.1016/j.intermet.2003.11.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The phase relation and microstructure of alloys based on Ni3Si-Ni3Ti-Ni3Nb pseudo-ternary alloy system at 1323 K were investigated by optical microscopy, X-ray diffraction and scanning electron microscopy (attached with a wavelength dispersive spectroscope). In high Ti concentration region, L1(2)(Ni3Si), B0(24)(Ni3Ti), D0a(Ni3Nb) and D0(19)(Ni3Ti0.7Nb0.3) were identified and then their phase fields were shown to depend upon the electron concentration (e/a) and the atomic size factor (R-x/R-Ni) of constituent atoms. Among four intermetallic phases identified, four kinds of two-phase relations (i.e. L1(2)-D0(24), D0(24)-D0(19), D0(19-)D0a and D0(19)-L1(2)) and two kinds of three-phase relations (i.e. L1(2)-D0(24)-D0(19) and L1(2)-D0(19)-D0a) were found to exist. In low Ti concentration region, a four-phase microstructure consisting of L1(2), D8a(Ni16Si7(Ti,Nb)(6)), D0a and Al(Ni solid solution) was observed to exist. The L1(2) phase cannot be directly equilibrated with the D0a phase. The prepared alloys exhibited widely different micro structures, depending on alloy compositions whether they exist in a single phase, a two-phase or a three-phase region, and also on constituent intermetallic phases. (C) 2003 Elsevier Ltd. All rights reserved.
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收藏
页码：317 / 325
页数：9
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