Levulinic acid: a sustainable platform chemical for novel polymer architectures

被引：91

作者：

Hayes, Graham C. ^{[1
]}

Becer, C. Remzi ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

POLYMER CHEMISTRY | 2020年 / 11卷 / 25期

关键词：

MEDIATED RADICAL POLYMERIZATION; MULTICOMPONENT REACTIONS; CATALYTIC CONVERSION; VINYL LEVULINATE; BIOMASS; CHEMISTRY; POLYAMIDES; MONOMER; FUELS; GREEN;

D O I：

10.1039/d0py00705f

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Levulinic acid is a multipurpose platform chemical that is currently used in a wide variety of applications. The potential of levulinic acid is formidable, as can be seen by the diversity and quantity of literature regarding its transformation into different chemicals. Development in industrial production of levulinic acid from lignocellulosic biomass has resulted in a surge of interest in levulinic acid as a cheap, readily available, biobased material. This minireview will analyse the application of levulinic acid as a reagent in polymer chemistry. Levulinic acid has been used in step-growth polymerization, chain-growth polymerization, as a post polymerization functionality, and finally as a method to introduce post polymerisation modificationto sustainable polymers.

引用

页码：4068 / 4077

页数：10

共 87 条

[1] (Co)Polymerization of vinyl levulinate by cobalt-mediated radical polymerization and functionalization by ketoxime click chemistry [J].

Allaoua, Imene ;

Goi, Beatriz Eleuterio ;

Obadia, Mona M. ;

Debuigne, Antoine ;

Detrembleur, Christophe ;

Drockenmuller, Eric .

POLYMER CHEMISTRY, 2014, 5 (08) :2973-2979

[2] Renewable polymers: Synthesis and characterization of poly(levulinic acid-pentaerythritol) [J].

Amarasekara, Ananda S. ;

Ha, Uyen ;

Okorie, Nnaemeka C. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2018, 56 (09) :955-958

[3] Synthesis of levulinic acid-glycerol ketal-ester oligomers and structural characterization using NMR spectroscopy [J].

Amarasekara, Ananda S. ;

Hawkins, Steven A. .

EUROPEAN POLYMER JOURNAL, 2011, 47 (12) :2451-2457

[4] A review on catalytic synthesis of energy rich fuel additive levulinate compounds from biomass derived levulinic acid [J].

Badgujar, Kirtikumar C. ;

Badgujar, Vivek C. ;

Bhanage, Bhalchandra M. .

FUEL PROCESSING TECHNOLOGY, 2020, 197

[5] Reductive Amination/Cyclization of Methyl Levulinate with Aspartic Acid: Towards Renewable Polyesters with a Pendant Lactam Unit [J].

Bernhard, Yann ;

Pellegrini, Sylvain ;

Bousquet, Till ;

Favrelle, Audrey ;

Pelinski, Lydie ;

Cazaux, Frederic ;

Gaucher, Valerie ;

Gerbaux, Pascal ;

Zinck, Philippe .

CHEMSUSCHEM, 2019, 12 (14) :3370-3376

[6] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[7] Application of functional diols derived from pentaerythritol as chain extenders in the synthesis of novel thermoplastic polyester-urethane elastomers [J].

Brannigan, Ruairi P. ;

Walder, Anthony ;

Dove, Andrew P. .

POLYMER CHEMISTRY, 2019, 10 (38) :5236-5241

[8] Cobalt-mediated radical polymerization (CMRP) of vinyl acetate initiated by redox systems:: Toward the scale-up of CMRP [J].

Bryaskova, Rayna ;

Detrembleur, Christophe ;

Debuigne, Antoine ;

Jerome, Robert .

MACROMOLECULES, 2006, 39 (24) :8263-8268

[9] Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing [J].

Carlos Serrano-Ruiz, Juan ;

Luque, Rafael ;

Sepulveda-Escribano, Antonio .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (11) :5266-5281

[10] Green Polymer Precursors from Biomass-Based Levulinic Acid [J].

Chalid, M. ;

Heeres, H. J. ;

Broekhuis, A. A. .

INTERNATIONAL CONFERENCE ON INNOVATION IN POLYMER SCIENCE AND TECHNOLOGY, 2012, 4 :260-267

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