Exploration of dielectric constant dependence on evolution of microstructure in nanotube/ferroelectric polymer nanocomposites

被引:37
作者
Yao, Sheng-Hong [1 ,2 ]
Dang, Zhi-Min [1 ,2 ]
Xu, Hai-Ping [1 ,2 ]
Jiang, Mei-Juan [2 ]
Bai, Jinbo [3 ]
机构
[1] Beijing Inst Chem Technol, Key Lab, Minist Educ Nanomat, Beijing 100029, Peoples R China
[2] Beijing Inst Chem Technol, Key Lab Beijing City Preparat & Possesing Novel M, Minist Educ Nanomat, Beijing 100029, Peoples R China
[3] Ecole Cent Paris, Lab MSSMAT, CNRS, UMR 8579, F-92295 Chatenay Malabry, France
基金
中国国家自然科学基金;
关键词
D O I
10.1063/1.2870104
中图分类号
O59 [应用物理学];
学科分类号
摘要
Multiwall carbon nanotube (MWNT) with high aspect ratio (AR=125-750) was dispersed into polyvinylidene fluoride (PVDF) to fabricate the MWNT/PVDF nanocomposites. Change of dielectric constant with increasing the length of tensile strain (LTS) was observed in the MWNT/PVDF composites with different mass concentration of MWNT (m(MWNT) = 1.0% and mMWNT = 2.0%). The results showed that an abrupt increase in dielectric constant appeared when the LTS was 4 and 2 mm in the composites with (m(MWNT) = 1.0% and m(MWNT) = 2.0%, respectively. By employing the evolutions of conductive pathway and microcapacitance structure during the tensile strain process, the increased dielectric constant could be explained well. (c) 2008 American Institute of Physics.
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页数:3
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