Synthesis and catalytic activity of binuclear titanium imido complexes

被引：16

作者：

Said, M ^{[1
]}

Hughes, DL ^{[1
]}

Bochmann, M ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci, Wolfson Mat & Catalysis Ctr, Norwich NR4 7TJ, Norfolk, England

来源：

DALTON TRANSACTIONS | 2004年 / 03期

关键词：

D O I：

10.1039/b315711c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the N-P ligand (ArN)-N-P(SiMe3)(2) with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(mu-NArP)](2) (Ar-P = m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of - PR2 functional groups.

引用

页码：359 / 360

页数：2

共 50 条

[21] Mono- and Binuclear Copper(I) Complexes of Thionucleotide Analogues and Their Catalytic Activity on the Synthesis of Dihydrofurans
Charalampou, D. C.
Kourkoumelis, N.
Karanestora, S.
Hadjiarapoglou, L. P.
Dokorou, V.
Skoulika, S.
Owczarzak, A.
Kubicki, M.
Hadjikakou, S. K.
INORGANIC CHEMISTRY, 2014, 53 (16) : 8322 - 8333
[22] Titanium complexes based on chiral enantiopure dialkanolamines: synthesis, structures and catalytic activity
Zaitsev, Kirill V.
Bermeshev, Maxim V.
Samsonov, Alexey A.
Oprunenko, Juri F.
Churakov, Andrei V.
Howard, Judith A. L.
Karlov, Sergey S.
Zaitseva, Galina S.
NEW JOURNAL OF CHEMISTRY, 2008, 32 (08) : 1415 - 1431
[23] Binuclear ruthenium(III) complexes: synthesis, characterisation, catalytic activity in aryl-aryl couplings and biological activity
Karvembu, R
Jayabalakrishnan, C
Dharmaraj, N
Renukadevi, SV
Natarajan, K
TRANSITION METAL CHEMISTRY, 2002, 27 (06) : 631 - 638
[24] Synthesis of Binuclear Ionic Liquids and Their Catalytic Activity for Esterification
Zhao, Dishun
Liu, Mengshuai
Ge, Jingjing
Zhang, Juan
Ren, Peibing
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2012, 32 (12) : 2382 - 2389
[25] SYNTHESIS OF BINUCLEAR BISGLYOXIME COMPLEXES FOR STOICHIOMETRIC AND CATALYTIC REDOX STUDIES
BOWERS, ML
HILL, CL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 246 - INOR
[26] Titanium hydrazido and imido complexes: Synthesis, structure, reactivity, and relevance to alkyne hydroamination
Li, YH
Shi, YH
Odom, AL
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (06) : 1794 - 1803
[27] (THFMgNPh)(6) as an imide transfer agent: Synthesis of titanium and zirconium imido complexes
Grigsby, WJ
Olmstead, MM
Power, PP
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 513 (1-2) : 173 - 180
[28] Synthesis and structure of new calix[4]arene titanium(IV) imido complexes
Radius, U
Friedrich, A
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (12): : 2154 - 2159
[29] Synthesis and structures of titanium(IV) imido complexes with dianionic ligands of triazapentadienyl derivatives
Wang, Xiaoyang
Guo, Zeling
Tong, Hongbo
Zhou, Meisu
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 828 : 10 - 15
[30] NEW AMIDO-TITANIUM AND IMIDO-TITANIUM COMPLEXES
VROEGOP, CT
TEUBEN, JH
BOLHUIS, F
VANDERLINDEN, JGM
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (10) : 550 - 552

← 1 2 3 4 5 →