A Durable and Self-Cleaning Superhydrophobic Surface Prepared by Precipitating Flower-Like Crystals on a Glass-Ceramic Surface

被引:17
作者
Fu, Haiqing [1 ,2 ,3 ]
Liu, Shuo [1 ,3 ]
Yi, Lanlin [1 ,2 ,3 ]
Jiang, Hong [1 ,2 ,3 ]
Li, Changjiu [1 ,2 ,3 ]
Chen, Yongjun [2 ,3 ]
机构
[1] Special Glass Key Lab Hainan Prov, Haikou 570228, Hainan, Peoples R China
[2] Hainan Univ, State Key Lab Marine Resource Utilizat South Chin, Haikou 570228, Hainan, Peoples R China
[3] Hainan Univ, Coll Mat Sci & Engn, Haikou 570228, Hainan, Peoples R China
关键词
glass-ceramic; crystallization; dual-scale roughness; superhydrophobic; durable; self-cleaning; NANOSECOND LASER; TRANSPARENT; CRYSTALLIZATION; FABRICATION; RESISTANCE; COATINGS;
D O I
10.3390/ma13071642
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, a superhydrophobic surface with superior durability was fabricated on a glass-ceramic surface by crystallization, hydrofluoric acid (HF) etching, and surface grafting. The as-prepared glass-ceramic surface was composed of three-dimensional flower-like micro-clusters, which were self-assembled from numerous nanosheets. Such a dual-scale rough surface exhibited superhydrophobicity, with a water contact angle (WCA) of 170.3 degrees +/- 0.1 degrees and a sliding angle (SA) of 2 degrees after grafting with 1H, 1H, 2H, 2H-perfluorodecyltriethoxysilane (FAS-17). This can be attributed to the synergistic effect between the dual-scale structure and surface chemistry. Furthermore, this surface exhibited excellent self-cleaning properties, stability against strong acid and strong alkali corrosion, and anti-stripping properties.
引用
收藏
页数:13
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