Organised chaos: entropy in hybrid inorganic-organic systems and other materials

被引：63

作者：

Butler, Keith T. ^{[1
]}

Walsh, Aron ^{[1
,2
]}

Cheetham, Anthony K. ^{[3
]}

Kieslich, Gregor ^{[3
]}

机构：

[1] Univ Bath, Dept Chem, Ctr Sustainable Chem Technol, Bath BA2 7AY, Avon, England

[2] Tohoku Univ, WPI Adv Inst Mat Res, Aoba Ku, 2-2-1 Katahira, Sendai, Miyagi 9808577, Japan

[3] Univ Cambridge, Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, England

来源：

CHEMICAL SCIENCE | 2016年 / 7卷 / 10期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

NEGATIVE THERMAL-EXPANSION; PHASE-TRANSITION; ELECTRONIC-PROPERTIES; SOLID-SOLUTION; FRAMEWORKS; DISORDER; CO2; ADSORPTION; BEHAVIOR; PHONONS;

D O I：

10.1039/c6sc02199a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Entropy is one of the fundamental quantities which links emerging research areas like flexibility and defect engineering in inorganic-organic hybrid materials. Additionally, a delicate balance between entropy and enthalpy can lead to intriguing temperature-driven transitions in such materials. Here, we briefly overview traditional material design principles, highlight the role of entropy in the past and discuss how computational methods can help us to understand and quantify entropic effects in inorganic-organic hybrid materials in the future.

引用

页码：6316 / 6324

页数：9

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