Commemorating Two Centuries of Iodine Research: An Interdisciplinary Overview of Current Research

被引:328
作者
Kuepper, Frithjof C. [1 ]
Feiters, Martin C. [2 ]
Olofsson, Berit [3 ]
Kaiho, Tatsuo [4 ]
Yanagida, Shozo [5 ]
Zimmermann, Michael B. [7 ]
Carpenter, Lucy J. [6 ]
Luther, George W., III [8 ]
Lu, Zunli [9 ]
Jonsson, Mats [10 ]
Kloo, Lars [10 ]
机构
[1] Scottish Assoc Marine Sci, Oban PA37 1QA, Argyll, Scotland
[2] Radboud Univ Nijmegen, Inst Mol & Mat, Dept Organ Chem, Nijmegen, Netherlands
[3] Stockholm Univ, Arrhenius Lab, Stockholm, Sweden
[4] Kanto Nat Gas Dev Co Ltd, Chiba, Japan
[5] Ctr Adv Sci & Innovat, Osaka, Japan
[6] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
[7] Swiss Fed Inst Technol, Zurich, Switzerland
[8] Univ Delaware, Coll Earth Ocean & Environm, Lewes, DE 19958 USA
[9] Syracuse Univ, Dept Earth Sci, Syracuse, NY 13244 USA
[10] KTH Royal Inst Technol, Dept Chem, SE-10044 Stockholm, Sweden
基金
英国自然环境研究理事会; 瑞典研究理事会; 美国国家科学基金会; 美国海洋和大气管理局;
关键词
environmental chemistry; history of chemistry; iodine; Mossbauer spectroscopy; X-ray spectroscopy; MARINE BOUNDARY-LAYER; ENANTIOSELECTIVE ALPHA-ARYLATION; CROSS-COUPLING REACTIONS; WEED LAMINARIA-DIGITATA; SENSITIZED SOLAR-CELLS; MOLECULAR-IODINE; DISSOLVED IODINE; IODATE REDUCTION; OXIDATIVE BURST; ORGANIC IODINE;
D O I
10.1002/anie.201100028
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Iodine was discovered as a novel element in 1811 during the Napoleonic Wars. To celebrate the bicentennial anniversary of this event we reflect on the history and highlight the many facets of iodine research that have evolved since its discovery. Iodine has an impact on many aspects of life on Earth as well as on human civilization. It is accumulated in high concentrations by marine algae, which are the origin of strong iodine fluxes into the coastal atmosphere which influence climatic processes, and dissolved iodine is considered a biophilic element in marine sediments. Iodine is central to thyroid function in vertebrates, with paramount implications for human health. Iodine can exist in a wide range of oxidation states and it features a diverse supramolecular chemistry. Iodine is amenable to several analytical techniques, and iodine compounds have found widespread use in organic synthesis. Elemental iodine is produced on an industrial scale and has found a wide range of applications in innovative materials, including semiconductorsin particular, in solar cells.
引用
收藏
页码:11598 / 11620
页数:23
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