Polyoxovanadate-Based Inorganic-Organic Derivatives Synthesized by the Activation of NHS Intermediate at Room Temperature

被引:4
作者
Xiao, Zicheng [1 ]
Huang, Bo [1 ]
Xu, Shuang [1 ]
Hu, Xiaokang [1 ]
Wu, Pingfan [1 ]
机构
[1] Hubei Univ Technol, Sch Mat & Chem Engn, Inst POM Based Mat, Hubei Prov Key Lab Green Mat Light Ind, Wuhan 430068, Hubei, Peoples R China
来源
CHEMISTRYSELECT | 2019年 / 4卷 / 05期
基金
中国国家自然科学基金;
关键词
Active ester intermediate; Amino acid; Crystal structure; Polyoxovanadates; N-HYDROXYSUCCINIMIDE; HYBRIDS; FUNCTIONALIZATION; HEXAVANADATE; RESOLUTION; CHEMISTRY; VERSATILE; CLUSTERS; SERIES;
D O I
10.1002/slct.201803729
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two novel polyoxovanadate-derived inorganic-organic hybrids were prepared by step-by-step modification via N-hydroxysuccinimide ester activation of a hexavanadate platform in this communication. Both the intermediate and products were structurally determined by IR, NMR, ESI-MS and single-crystal X-ray diffraction. This work provides a new vision for the synthesis of polyoxovanadate-based amino acids.
引用
收藏
页码:1742 / 1744
页数:3
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