Hydrothermal synthesis of Ni(OH)2 nanoflakes on 3D graphene foam for high-performance supercapacitors

被引:87
作者
Jiang, Chuan [1 ]
Zhao, Bin [1 ]
Cheng, Junye [1 ]
Li, Jianqiang [2 ]
Zhang, Huijuan [1 ]
Tang, Zhihong [1 ]
Yang, Junhe [1 ]
机构
[1] Univ Shanghai Sci & Technol, Sch Mat Sci & Engn, Shanghai 200093, Peoples R China
[2] Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
关键词
Ni(OH)(2); 3D graphene; supercapacitor; hydrothermal reaction; CHEMICAL-VAPOR-DEPOSITION; ELECTRODE MATERIALS; OXIDE; SUBSTRATE; NETWORKS; FILMS;
D O I
10.1016/j.electacta.2015.05.081
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Ni(OH)(2) nanoflakes were successfully synthesized with a facile hydrothermal method on 3D (three-dimensional) graphene grown by atmospheric pressure chemical vapor deposition (APCVD). The hydrothermal temperature and time were optimized to improve the performance of the composite as a binder-free supercapacitor electrode. The Ni(OH)(2)/3D graphene composite synthesized at 180 degrees C for 3 h shows high specific capacitance of 1450 F/g at a current density of 5 A/g. Even when the discharge current density increases to 60 A/g, a specific capacitance of 1196 F/g is still retained, highlighting the remarkable rate capability of our composite electrode. It also shows good capacity retention of 78 % after 1000 charge-discharge cycles, presenting the excellent cycle stability. These impressive results suggest that the composite is a promising electrode material for high-performance supercapacitors. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:399 / 407
页数:9
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