Synthesis and characterization of three Cd(II) Schiff-base macrocyclic N3O2 complexes

被引：15

作者：

Keypour, Hassan ^{[1
]}

Azadbakht, Reza ^{[1
]}

Khavasi, Hamidreza ^{[2
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Hamadan, Iran

[2] Shahid Beheshti Univ, Dept Chem, Tehran, Iran

来源：

POLYHEDRON | 2008年 / 27卷 / 02期

关键词：

macrocyclic complexes; schiff-base; crystal structure; NMR spectroscopy;

D O I：

10.1016/j.poly.2007.10.029

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three polyamine ligands of N1-(2-nitrobenzyl)-N1-(2-aniinoethyl)ethane-1,2-diamine (L-1), N1-(2-nitrobenzyl)-N1-(2-aniinoethyl)propane-1,3-diamine (L-2) and N1-(2-nitrobenzyl)-N1-(3-aniinopropyl)propane-1,3-diamine (L-3) were synthesized and their cyclocondensation with 2-[2-(2-formyl phenoxy)ethoxy]benzaldehyde (L-4) in the presence of various metal(II) ions was examined. These reactions only in the presence of a stoichiometric amount of cadmium(II) nitrate gave the related cadmium(II) macrocyclic Schiff-base complexes. In all the other cases no cyclic complexes have been obtained and metal(II) polyamines were the only products. The complexes have been studied with IR, H-1 NMR, C-13 NMR, DEPT, COSY, HMQC and microanalysis. The crystal structures of [Cd(NO3)(L-5)(mu-NO3)Cd(NO3)(L-5)]0.5Cd(NO3)(4) (1) and [CdL5(NO3)(CH3OH)]ClO4 (2) have been also determined. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：648 / 654

页数：7

共 50 条

[1] Synthesis, characterization, and antioxidant activities of three Cu(II) complexes with Schiff-base ligands
Wang, Yuan
Wu, Wei-Na
Wang, Qian
Yang, Zheng-Yin
JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (01) : 147 - 155
[2] Synthesis and characterization of macrocyclic zinc(II) complexes containing Schiff base
Keypour, Hassan
Araey, Farzaneh Azizzadeh
ASIAN JOURNAL OF CHEMISTRY, 2007, 19 (04) : 2873 - 2876
[3] Synthesis, spectroscopy, electrochemistry and thermal study of uranyl N3O2 Schiff base complexes
Kianfar, Ali Hossein
Boudani, Mostafa Kazemi
Roushani, Mahmoud
Shamsipur, Mojtaba
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2012, 9 (04) : 449 - 453
[4] Synthesis, characterization, and spectroscopy of two new macrocyclic Schiff base Cd(II) complexes
Golbedaghi, Reza
Salehi, Alirza
IRANIAN CHEMICAL COMMUNICATION, 2018, 6 (01) : 78 - 86
[5] Manganese(II) Macrocyclic Schiff-Base Complexes Containing Pyridine Moiety: Synthesis and Characterization and Antibacterial Properties
Hassan, Keypour
Mozhdeh, Liyaghati-Delshad
Majid, Rezaeivala
Reza, Khavasi Hamid
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (07) : 1733 - 1740
[6] A Series of Novel Pentagonal-Bipyramidal Erbium(III) Complexes with Acyclic Chelating N3O2 Schiff-Base Ligands: Synthesis, Structure, and Magnetism
Bazhenova, Tamara A.
Kopotkov, Vyacheslav A.
Korchagin, Denis V.
Manakin, Yuriy V.
Zorina, Leokadiya V.
Simonov, Sergey V.
Yakushev, Ilya A.
Mironov, Vladimir S.
Vasiliev, Alexander N.
Maximova, Olga V.
Yagubskii, Eduard B.
MOLECULES, 2021, 26 (22):
[7] Synthesis, crystal structure, spectral characterization and photoluminescence property of three Cd(II) complexes with a pyrazole based Schiff-base ligand
Mandal, Susmita
Saha, Rajat
Saha, Manan
Pradhan, Rajesh
Butcher, Ray J.
Saha, Nitis Chandra
JOURNAL OF MOLECULAR STRUCTURE, 2016, 1110 : 11 - 18
[8] Synthesis, structure and catalase activity of three new manganese(III) complexes with a N,N,O donor Schiff-base ligand
Kar, Paramita
Drew, Michael G. B.
Ghosh, Ashutosh
INORGANICA CHIMICA ACTA, 2013, 405 : 349 - 355
[9] Synthesis, spectral characterization and antimicrobial activity of macrocyclic Schiff-base copper(II) complexes containing polycrystalline nanosized grains
Raman, N.
Joseph, J.
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (07) : 1162 - 1171
[10] Synthesis, characterization, anticancer properties and theoretical study of asymmetrical Cd(II)-N2-Schiff base complexes
Saedi, Zahra
Hoveizi, Elham
Roushani, Mahmoud
Massahi, Shokofeh
Hadian, Mohammad
Salehi, Khadijeh
JOURNAL OF MOLECULAR STRUCTURE, 2019, 1176 : 207 - 216

← 1 2 3 4 5 →