Some comments on nature of the structural relaxation and glass transition

被引:3
作者
Danch, A. [1 ]
机构
[1] Univ Slaski, Inst Fizyki Zaklad Biofizyki & Fizyki Mol, PL-40007 Katowice, Poland
关键词
glass transition; relaxation time; structural heterogeneity;
D O I
10.1007/s10973-007-8651-1
中图分类号
O414.1 [热力学];
学科分类号
摘要
We report on an experiment and new formula revealing dynamic and structural heterogeneity observed in liquids and polymeric systems. The formula applied to data obtained by mechanical spectroscopy reveals the glass-forming system behaviour giving the parameters previously postulated. The presented results are compared with data obtained for liquids (oligomers) confined to nanoporous media. To explain the behaviour of the polymeric systems the three-phase model is considered.
引用
收藏
页码:733 / 736
页数:4
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