Metal-free cascade reactions of aziridines with arylalkynes and aryldiazoniums: facile access to arylazopyrrolines

被引：10

作者：

Rong, Jing ^{[1
]}

Jiang, Hao ^{[1
]}

Wang, Sijing ^{[1
]}

Su, Zhenni ^{[1
]}

Wang, Huiyan ^{[1
]}

Tao, Chuanzhou ^{[1
]}

机构：

[1] Jiangsu Ocean Univ, Sch Chem Engn, Lianyungang 222005, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 16期

基金：

中国国家自然科学基金;

关键词：

MUTUAL AZO PRODRUGS; 2,3-DIHYDROPYRROLES; DESIGN; AGENTS; ACID; DERIVATIVES; CYCLIZATION; INHIBITORS; ASSEMBLIES; COMPLEXES;

D O I：

10.1039/d0ob00346h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and facile approach to synthesize arylazopyrroline scaffolds via metal-free cascade reactions of aziridines with arylalkynes and aryldiazoniums has been developed, providing access to a variety of 4-arylazo-2-pyrrolines in a highly concise fashion. This efficient process, which can be performed at the gram scale, enjoys operational simplicity and mild and metal-free conditions.

引用

页码：3149 / 3157

页数：9

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