{Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ3P,P′,P"}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate

被引：2
|
作者：
Zhao, Shu-Bin [1 ]
Wang, Rui-Yao [2 ]
Gagne, Michel R. [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
[2] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
D O I：
10.1107/S1600536811023853
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title ionic compound, [Pt(C17H23)(C34H33P3)](BF4)center dot-2CH(2)Cl(2), the Pt-II atom adopts a square-planar coordination geometry with the large (Z)-8-mesitylcyclooct-4-en-1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclooct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF4)(-) anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.
引用
收藏
页码：M972 / U1407
页数：16
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