Template-Free Synthesis and Photocatalytic Application of Rutile TiO2 Hierarchical Nanostructures

被引：65
作者：
Ge, M. [1 ]
Li, J. W. [1 ]
Liu, L. [1 ]
Zhou, Z. [2 ,3 ]
机构：
[1] Nankai Univ, Tianjin Key Lab Environm Remediat & Pollut Contro, Tianjin 300071, Peoples R China
[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
[3] Nankai Univ, Inst New Energy Mat Chem, Tianjin 300071, Peoples R China
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2011年 / 50卷 / 11期
关键词：
AZO-DYE; TEMPERATURE SYNTHESIS; HYDROGEN-PEROXIDE; DEGRADATION; OXIDATION; SURFACES; NANORODS; ORANGE; PHOTOOXIDATION; FABRICATION;
D O I：
10.1021/ie1023113
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A simple template-free hydrothermal method was employed to synthesize flower-shaped single-crystal rutile TiO2 hierarchical nanostructures without calcination process. Scanning electron microscope and transmission electron microscope images show that rutile TiO2 nanostructures with diameters of 1-1.5 mu m are composed of nanorods with a wimble shape. The band gap of the as-prepared rutile TiO2 is about 3.02 eV by ultraviolet-visible absorption spectrum. The photocatalytic performance of the as-obtained samples as catalysts for Rhodamine B (RhB) degradation under simulated solar light was greatly enhanced with the assistance of a small amount of H2O2. In the H2O2-containing system, the as-prepared rutile TiO2 photocatalyst was more efficient in the photodegradation of RhB than commercial P25. The stability and recycle of the rutile TiO2/H2O2 system were also investigated.
引用
收藏
页码：6681 / 6687
页数：7
相关论文
共 44 条
  • [1] H2O2/TiO2 photocatalytic oxidation of metol.: Identification of intermediates and reaction pathways
    Aceituno, M
    Stalikas, CD
    Lunar, L
    Rubio, S
    Pérez-Bendito, D
    [J]. WATER RESEARCH, 2002, 36 (14) : 3582 - 3592
  • [2] Heterogeneous photocatalytic treatment of simulated dyehouse effluents using novel TiO2-photocatalysts
    Arslan, I
    Balcioglu, IA
    Bahnemann, DW
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 26 (03) : 193 - 206
  • [3] Characterization of the hydrothermally synthesized nano-TiO2 crystallite and the photocatalytic degradation of Rhodamine B
    Asiltürk, M
    Sayilkan, F
    Erdemoglu, S
    Akarsu, M
    Sayilkan, H
    Erdemoglu, M
    Arpaç, E
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2006, 129 (1-3) : 164 - 170
  • [4] Photooxidation of an azo dye induced by visible light incident on the surface of TiO2
    Bauer, C
    Jacques, P
    Kalt, A
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 140 (01) : 87 - 92
  • [5] Photochemical oxidation processes for the elimination of phenyl-urea herbicides in waters
    Benitez, F. Javier
    Real, Francisco J.
    Acero, Juan L.
    Garcia, Carolina
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2006, 138 (02) : 278 - 287
  • [6] ADSORPTION OF HYDROGEN-PEROXIDE ON SURFACE OF TITANIUM-DIOXIDE
    BOONSTRA, AH
    MUTSAERS, CAHA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (18) : 1940 - 1943
  • [7] Degradation of 1,4-dioxane in water using TiO2 based photocatalytic and H2O2/UV processes
    Coleman, H. M.
    Vimonses, V.
    Leslie, G.
    Amal, R.
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2007, 146 (03) : 496 - 501
  • [8] PHOTOCHEMICAL FORMATION OF HYDROGEN-PEROXIDE IN SURFACE AND GROUND WATERS EXPOSED TO SUNLIGHT
    COOPER, WJ
    ZIKA, RG
    [J]. SCIENCE, 1983, 220 (4598) : 711 - 712
  • [9] Photocatalytic degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution using UV/TiO2 and UV/H2O2/TiO2 photocatalysis
    Elmolla, Emad S.
    Chaudhuri, Malay
    [J]. DESALINATION, 2010, 252 (1-3) : 46 - 52
  • [10] Fujishima A., 2000, J PHOTOCH PHOTOBIO C, V1, P1, DOI DOI 10.1016/S1389-5567(00)00002-2
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