Crystal structure and fluorescence of a novel 3D inorganic-organic hybrid polymer with mixed ligands

被引：38
作者：
Liu, XJ
Fang, QR
Zhu, GS [1 ]
Xue, M
Shi, X
Wu, G
Tian, G
Qiu, SL
Fang, L
机构：
[1] Coll Pharmaceut Engn, Key Lab Inorgan, Shenyang 110016, Peoples R China
[2] Jilin Univ, Changchun 130023, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 01期
基金：
中国国家自然科学基金;
关键词：
inorganic-organic hybrid polymer; crystal structure; fluorescence; mixed ligands;
D O I：
10.1016/j.inoche.2003.09.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new inorganic-organic hybrid polymer [Cd-3(CTC)(2)(4,4'-bipy)(2)(C2H5OH)(2)](n), (1) (CTC = cis,cis-1,3,5-cyclohexanetricarboxylate and 4,4'-bipy = 4,4'-bipyridine) that exhibits intense fluorescent property was synthesized under appropriate conditions and characterized by single-crystal X-ray diffraction, which revealed a 3D architecture formed by 4,4'-bipy ligands interlinked adjacent 2D sheets [Cd-3(CTC)(2)(C2H5OH)(2)](n). (C) 2003 Elsevier B.V. All rights reserved.
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收藏
页码：31 / 34
页数：4
相关论文
共 30 条
  • [1] Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO
  • [2] 2-Y
  • [3] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores
    Chen, BL
    Eddaoudi, M
    Hyde, ST
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2001, 291 (5506) : 1021 - 1023
  • [4] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
    Chui, SSY
    Lo, SMF
    Charmant, JPH
    Orpen, AG
    Williams, ID
    [J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
  • [5] THE POLYMERIC STRUCTURE OF AQUACADMIUM BISNICOTINATE
    CLEGG, W
    CRESSEY, JT
    MCCAMLEY, A
    STRAUGHAN, BP
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 234 - 235
  • [6] A novel ribbon-candy-like supramolecular architecture of cadmium(II)-terephthalate polymer with giant rhombic channels:: twofold interpenetration of the 3D 8210-a net
    Dai, JC
    Wu, XT
    Fu, ZY
    Hu, SM
    Du, WX
    Cui, CP
    Wu, LM
    Zhang, HH
    Sun, RQ
    [J]. CHEMICAL COMMUNICATIONS, 2002, (01) : 12 - 13
  • [7] Evans OR, 1999, ANGEW CHEM INT EDIT, V38, P536, DOI 10.1002/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO
  • [8] 2-3
  • [9] ONE-DIMENSIONAL COORDINATE POLYMER INVOLVING HEPTACOORDINATE CADMIUM(II) IONS
    FUJITA, M
    KWON, YJ
    MIYAZAWA, M
    OGURA, K
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (17) : 1977 - 1978
  • [10] Kumagai H, 2001, J MATER CHEM, V11, P2146, DOI 10.1039/b101531l
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