Syntheses of conjugated polymers derived from N-alkyl-2,7-carbazoles

被引：325

作者：

Morin, JF ^{[1
]}

Leclerc, M ^{[1
]}

机构：

[1] Univ Laval, Ctr Rech Sci & Ingn Macromol, Dept Chem, Canada Res Chair Polymer Chem, Quebec City, PQ G1K 7P4, Canada

来源：

MACROMOLECULES | 2001年 / 34卷 / 14期

关键词：

D O I：

10.1021/ma010152u

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Syntheses of conjugated polymers derived from N-Alkyl-2,7-carbazoles were analyzed. Homopolymerizations were achieved by a reductive Yamamoto reaction using N-alkyl-2,7-dihalogenocarbazoles as starting materials in the presence of triphenylphosphine, zinc, 2,2′-bipyridine and NiCl2. The physical properties of homopolymers and copolymers derived from the carbazoles were studied. Analysis showed that the polymers were capable of finding application in electrical, electrochemical, optical and electrooptical devices.

引用

页码：4680 / 4682

页数：3

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