Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H-H, B-H and C=C bonds with B(C6F5)3 and boryl-borate lithium

被引：19
|
作者：
Zheng, Junhao [1 ]
Wang, Yuwen [1 ]
Li, Zhen Hua [1 ]
Wang, Huadong [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 25期
关键词：
HETEROLYTIC DIHYDROGEN ACTIVATION; ACID-BASE PAIRS; HYDROGEN; REACTIVITY; BORENIUM; CARBENE; CARBON; ALDEHYDES; ADDITIONS; KETONES;
D O I：
10.1039/c4cc07658c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The frustrated Lewis pair comprised of B(C6F5)(3) and a boryl-borate lithium salt Li[pinBB(Ph)pin] can efficiently activate dihydrogen, pinacolborane and ethylene at ambient temperature. Theoretical studies suggest that the nucleophilic sp(2) boryl moiety of Li[pinBB(Ph)pin] plays different roles in these reactions.
引用
收藏
页码：5505 / 5508
页数：4
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