Hydrothermal synthesis of Boron -doped porous carbon from Azadirachta Indica wood for supercapacitor application

被引:24
作者
Poornima, B. H. [1 ]
Vijayakumar, T. [1 ]
机构
[1] SRM Inst Sci & Technol, Coll Engn & Technol, Fac Engn & Technol, Futurist Mat Res Ctr Planetary Explorat,Dept Phys, Kancheepuram 603203, Tamil Nadu, India
关键词
Supercapacitor; Carbon material; Boron doping; Activated carbon; Azadirachta Indica wood; ACTIVATED CARBON; PYROLYSIS TEMPERATURE; OXYGEN REDUCTION; PERFORMANCE; ELECTRODE; WASTE; STRATEGY; FIBER; ADSORPTION; LIGNIN;
D O I
10.1016/j.inoche.2022.109953
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Natural bio waste Azadirachta Indica wood produces highly microporous carbon material by a simple one-step process using KOH as a precursor for activation of carbon and boric acid as a boron source for doping boron with Activated Carbon. Boric acid is added to the carbon frame work, which not only incorporates some boron but also enhances the carbon based materials specific surface area. The prepared B-doped microporous carbon possesses a huge surface area (1503.7 m(2)/g) and numerous strongly interconnected micropores due to the nanostructured boron doping. This boron doped carbon material has a high specific capacitance of 285.6 Fg(-1) at 1Ag(-1), and better cyclic performance with 98% retention after 5000 cycles, due to the synergetic effect of huge surface area and highly developed distribution of pore size. The developed flexible asymmetric supercapacitor has an energy density of 87.7 Whkg(-1) and a power density of 4000 WKg(-1). Evidently, this work paves the way for worthy recycling of biowaste materials by providing a simple and cost-effective pathway for synthesizing functionalized biowaste-based carbon materials.
引用
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页数:12
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