Synthesis of iron and vanadium incorporated SBA-15 molecular sieves and its catalysis for Hydroxylation of benzene

被引：0

作者：

Gu Ying-Ying ^{[1
]}

Li Jiang ^{[1
]}

Zhao Xin-Hua ^{[1
]}

Wang Li-Ping ^{[1
]}

Shan Yong-Kui ^{[1
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China

来源：

ACTA CHIMICA SINICA | 2007年 / 65卷 / 21期

关键词：

SBA-15; mesoporous molecular sieves; bimetallic modification; benzene; hydroxylation;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bimetallic iron and vanadium incorporated SBA-15 molecular sieves (FVS) has been hydrothermally synthesized. XRD, TEM and N-2 adsorption-desorption results show that the FVS catalyst has a 2D P6mm hexagonal structure. ESR and UV-vis spectroscopic investigations suggested that the tetrahedrally coordinated iron and. vanadium species incorporated within the silica framework. The FVS catalyst exhibited high activity toward hydroxylation of benzene with molecular oxygen, over which the yield of phenol reaches 14.5%.

引用

页码：2423 / 2427

页数：5

共 27 条

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