Photo-CIDNP Spectroscopy

被引：81

作者：

Goez, Martin ^{[1
]}

机构：

[1] Univ Halle Wittenberg, Inst Chem, D-06120 Halle, Germany

来源：

ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 66 | 2009年 / 66卷

关键词：

Chemically induced dynamic nuclear polarization; Photochemistry; Paramagnetic NMR; NMR in reacting systems; DYNAMIC NUCLEAR-POLARIZATION; TIME-RESOLVED CIDNP; LASER FLASH-PHOTOLYSIS; PHOTOSYNTHETIC REACTION CENTERS; RADICAL-ION PAIRS; PHOTOINDUCED ELECTRON-TRANSFER; MAGNETIC-FIELD DEPENDENCE; AROMATIC-AMINO-ACIDS; TRANSFER SENSITIZED PHOTOLYSIS; INTRAMOLECULAR CHARGE-TRANSFER;

D O I：

10.1016/S0066-4103(08)00403-1

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Photo-CIDNP spectroscopy relies on a unique interplay of magnetic interactions, diffusion, and chemical reactivity; it possesses all the advantages of NMR spectroscopy but responds to processes on a nanosecond timescale. This very powerful method can be used to investigate short-lived intermediates, the mechanisms of complex photoreactions, structures and folding of proteins, and processes in photosynthetic reaction centres. This chapter provides an introduction to the theory, explains the instrumentation and techniques with emphasis on new developments, uses a series of case studies to illustrate the information that a chemist can obtain from photo-CIDNP, and reviews recent applications of photo-CIDNP spectroscopy to chemical and biochemical problems. The literature from 1996 to mid-2008 is covered.

引用

页码：77 / 147

页数：71

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