Patterning 2D materials for devices by mild lithography

被引:8
作者
Weinhold, Marcel
Klar, Peter J. [1 ]
机构
[1] Justus Liebig Univ Giessen, Inst Expt Phys 1, Heinrich Buff Ring 16, DE-35392 Giessen, Germany
关键词
RAMAN-SPECTROSCOPY; ELECTRON-TRANSFER; GRAPHENE;
D O I
10.1039/d1ra04982h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2D materials have been intensively studied for almost two decades and are now exhibiting exceptional properties. Thus, devices that integrate 2D materials offer many novel functionalities that will contribute significantly to the transition into an era beyond 'Moore'. Lithographic methods are key technologies in the context of materials' integration into devices. However, to fully leverage the capabilities of these potential devices, it is vital to keep the integrity of the 2D materials intact and to minimize damage induced by device processing. This requirement is only partially met when employing conventional lithography methods, as they induce structural defects in the delicate materials. We demonstrate that exposing graphene to typical electron doses used in conventional electron beam lithography induces significant defect formation. The defect density is proportional to the electron dose and the structural integrity cannot be fully recovered by thermal annealing. We introduce a novel approach of mild lithography which combines traditional processing methods with a subsequent transfer step of the patterned mask onto the 2D material. We demonstrate that this separation of pattern definition and pattern application allows the lithographic process to be performed without exposing and potentially damaging the 2D material being processed. Finally, as an example relevant in terms of innovative device architectures, we present how the mild lithography approach can be used to achieve ordered arrangements of gold nanoparticles on 2D materials.
引用
收藏
页码:29887 / 29895
页数:9
相关论文
共 61 条
[11]   2-DIMENSIONAL CRYSTALLIZATION [J].
DENKOV, ND ;
VELEV, OD ;
KRALCHEVSKY, PA ;
IVANOV, IB ;
YOSHIMURA, H ;
NAGAYAMA, K .
NATURE, 1993, 361 (6407) :26-26
[12]   A surface-enhanced Raman-spectroscopic study: Verification of the interparticle gap dependence of field enhancement by triangulation of spherical gold nanoparticle trimers [J].
Dort, Katharina ;
Kroth, Kathrin ;
Klar, Peter J. .
JOURNAL OF RAMAN SPECTROSCOPY, 2019, 50 (12) :1807-1816
[13]   Raman study on defective graphene: Effect of the excitation energy, type, and amount of defects [J].
Eckmann, Axel ;
Felten, Alexandre ;
Verzhbitskiy, Ivan ;
Davey, Rebecca ;
Casiraghi, Cinzia .
PHYSICAL REVIEW B, 2013, 88 (03)
[14]   Plasmon-Induced Doping of Graphene [J].
Fang, Zheyu ;
Wang, Yumin ;
Liu, Zheng ;
Schlather, Andrea ;
Ajayan, Pulickel M. ;
Koppens, Frank H. L. ;
Nordlander, Peter ;
Halas, Naomi J. .
ACS NANO, 2012, 6 (11) :10222-10228
[15]   Graphene-Antenna Sandwich Photodetector [J].
Fang, Zheyu ;
Liu, Zheng ;
Wang, Yumin ;
Ajayan, Pulickel M. ;
Nordlander, Peter ;
Halas, Naomi J. .
NANO LETTERS, 2012, 12 (07) :3808-3813
[16]   Interpretation of Raman spectra of disordered and amorphous carbon [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107
[17]   Raman spectroscopy as a versatile tool for studying the properties of graphene [J].
Ferrari, Andrea C. ;
Basko, Denis M. .
NATURE NANOTECHNOLOGY, 2013, 8 (04) :235-246
[18]   Electron beam nanosculpting of suspended graphene sheets [J].
Fischbein, Michael D. ;
Drndic, Marija .
APPLIED PHYSICS LETTERS, 2008, 93 (11)
[19]   Template-assisted electrodeposition of Ni and Ni/Au nanowires on planar and curved substrates [J].
Guiliani, Jason ;
Cadena, John ;
Monton, Carlos .
NANOTECHNOLOGY, 2018, 29 (07)
[20]   Mechanical and thermal transport properties of graphene with defects [J].
Hao, Feng ;
Fang, Daining ;
Xu, Zhiping .
APPLIED PHYSICS LETTERS, 2011, 99 (04)